Rhodium Carbonyl Chloride 四羰基二氯化二铑

CAS 14523-22-9 MFCD00135610

化学结构图

14523-22-9
SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Cl+]1[Rh-][Cl+][Rh-]1

化学属性

Mol. Formula[Rh(CO)2Cl]2
Mol. Weight388.76
Melting Point120-125 °C (dec.)(lit.)
TSCANo

别名和识别编码

Chemical NameRhodium Carbonyl Chloride
Synonym Rhodium, tetracarbonyldi-μ-chlorodi- CHLORODICARBONYLRHODIUM(I) DIMER Chlorodicarbonylrhodium dimer Rhodium dicarbonyl chloride dimer Rhodium carbonyl chlor Di-μ-chloro-tetracarbonyldirhodium Tetracarbonyl-μ,μ'-dichlorodirhodium Di-my-chloro-tetracarbonyldirhodium Tetracarbonyldi-μ-chlorodirhodi DI-MU-CHLORO-TETRACARBONYLDIRHODIUM CHLORODICARBONYL RHODIUM (II) DIMER Tetracarbonyldichlorodirhodium TETRACARBONYLDI-U-CHLORODIRHODIUM(I) Tetracarbonyl-μ-dichlorodirhodium Rhodium, tetracarbonyldichlorodi-, co Bis(dicarbonylrhodium chloride) Rhodium(I)-dicarbonylchlori BIS(CHLORODICARBONYL)RHODIUM Rhodium, tetrakis(carbonyl)dichlorodi- {Chemb mu-Dichlorotetracarbonyldirhodium μ-Dichlorotetracarbonyldirhodium {uni Chlorodicarbonylrhodium(I) dimer Rhodium, tetracarbonyltetrachlorodi- Tetracarbonyl-μ,μ'-dichlorodirhodium(I) Bis(dicarbonyl(μ-chloro)rhodium) Di-micron-chloro-tetracarbonyldirhodium di-μ-chloro-bis(dicarbonylrhodium) Tetracarbonyldi-μ-chlorodirhodium(I) {uni_ 四羰基-μ-氯二铑(I) Tetracarbonyl dichlorodirhod Bis(chlororhodiumdicarbonyl) Dicarbonylrhodium chloride dimer Rhodium, tetracarbonyltetrachl RHODIUM(I) DICARBONYL CHLORIDE DIMER Rhodium carbonyl chloride (Rh2(CO)4C Chlororhodium dicarbonyl dimer Tetracarbonyl-μ, μ'-dichlorodirhodium TETRACARBONYLDI-MU-CHLORODIRHODIUM(I) Dichlorodirhodiumtetracarbonyl 二羰基氯铑二聚体 二-μ-
MDL NumberMFCD00135610
PubChem Substance ID24852228
EC Number238-540-6
CAS Number14523-22-9
Merck Number14,8187
Chemical Name Translation四羰基二氯化二铑
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium Catalysts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium
  • {uni_hamburg} no charge; metal-organic; other heterocycle; alicycle; fused rings; 3ring; 4ring; metal carbonyl; 1fragment

相关文献及参考

  • Short: III/35D5 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 5: Organometallic Compounds Author: Mikhova, Bozhana Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D5 Year: 2008 Keyword: Carbon-13; chemical shift; magnetic properties of nuclei; nuclear magnetic resonance data ISBN: 978-3-540-74188-6 (print) ISBN: 978-3-540-74189-3 (electronic) Internet Resource: DOI:10.1007/978-3-540-74189-3 RefComment: VIII, 241 p., Hardcover RefComment: Written for Scientists and engineers in the fields of physics, chemistry and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei 11B and 31P, subvolume III/35B contains the nuclei 19F and 15N, subvolume III/35C contains the nucleus 1H, subvolume III/35D contains the nucleus 13C, subvolume III/35E contains the nucleus 17O, and subvolume III/35G contains the nucleus 77Se. More nuclei will be presented later.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Packing GroupIII
UN Number UN3466
Risk Statements
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
  • R22 Harmful if swallowed 吞咽有害
Storage condition Air & Moisture Sensitive
Hazard Codes T
Hazard Class6.1

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhenium

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