(R,R)-DUTHALER-HAFNER REAGENT 氯环戊二烯基[(4R,5R)-2,2-二甲基-α,α,α′,α′-四苯基-1,3-二氧戊环-4,5-二甲醇酸根]钛

CAS 132068-98-5 MFCD00143370

化学结构图

132068-98-5
SMILES: CC1(C)O[C@H](OC(C2C=CC=CC=2)C2C=CC=CC=2)[C@H](O1)OC(C1C=CC=CC=1)C1C=CC=CC=1.Cl[Ti].[CH]1[CH][CH][CH][CH]1 |^1:37,38,39,40,41|

化学属性

Mol. FormulaC36H33ClO4Ti
Mol. Weight612.96
Melting Point209-213 °C (lit.)

别名和识别编码

Chemical NameChlorocyclopentadienyl[(4R,5R)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium
Synonym (R,R)-Duthaler-Hafner 试剂 (4R,5R)-氯-环戊二烯基-[2,2-二甲基-1,3-二氧戊环-4,5-双(二苯基甲氧基)]钛 (R,R)-Duthaler-Hafner reagent [(4R,5R)-2,2-Dimethyl-1,3-dioxolan-4,5-bis(diphenylmethoxy)]cyclopentadienyl-chlorotitanium (4R,5R)-氯-环戊二烯基-[2,2-二甲基-1,3-二氧戊环-4,5-双(二苯基甲氧基)]钛 (R,R)-Duthaler-Hafner 试剂 [(4R,5R)-2,2-二甲基-1,3-二氧戊环-4,5-双(二苯基甲氧基)]环戊二烯基-氯化钛 [(4R,5R)-2,2-二甲基-1,3-二氧戊环-4,5-双(二苯基甲氧基)]环戊二烯基-氯化钛 氯环戊二烯基[(4R,5R)-2,2-二甲基-α,α,α′,α′-四苯基-1,3-二氧戊环-4,5-二甲醇酸根]钛
PubChem Substance ID24868488
CAS Number132068-98-5
MDL NumberMFCD00143370
Chemical Name Translation氯环戊二烯基[(4R,5R)-2,2-二甲基-α,α,α′,α′-四苯基-1,3-二氧戊环-4,5-二甲醇酸根]钛
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Allylation, Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, TADDOLs

相关文献及参考

  • 1. Hafner, A. et al. J. Am. Chem. Soc. 114 , 2321, (1992)
  • 2. Duthaler, R.O. Hafner, A. Chem. Rev. 92 , 807, (1992)
  • 3. Duthaler, R.O. et al. Pure Appl. Chem. 64 , 1897, (1990)
  • 4. Duthaler, R.O. et al. Inorg. Chim. Acta 222 , 95, (1994)
  • 5. Duthaler, R.O. et al. Pure Appl. Chem. 62 , 631, (1990)
  • Merck 14 ,3472
  • FT-IR 2 (3), 4571:B

安全信息

Hazard Codes C
WGK Germany3
GHS Symbol
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R34 Causes burns 会导致灼伤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Allylation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. TADDOLs - Privileged Ligands and Complexes

相关产品推荐