4-Methylmorpholine N-Oxide Monohydrate 4-甲基吗啡-N-氧化物一水合物
CAS 70187-32-5 MFCD00149388
化学结构图
SMILES: C[N+]1([O-])CCOCC1
化学属性
| Mol. Formula | C5H13NO3 |
|---|---|
| Mol. Weight | 135 |
| Melting Point | 73-75 |
| TSCA | Yes |
| Density | 1.422 |
| Stability | 易吸湿 |
| Appearance | 淡黄晶体，吸湿。类似氨臭味，熔点: 71℃，自燃温度 130℃，凝固点 -20℃，易溶于水,密度: 1.14 |
别名和识别编码
| Chemical Name | 4-Methylmorpholine N-Oxide Monohydrate |
|---|---|
| MDL Number | MFCD00149388 |
| Synonym | N-Methylmorpholine N-oxide monohydrate~NMMO 4-METHYLMORPHOLINE-OXIDE MONOHYDRATE 4-METHYL-1,4-OXAZINAN-4-IUM-4-OLATE HYDRATE N-METHYLMORPHOLINE N-OXIDE MONOHYDRATE N-METHYLMORPHOLINE-N-OXIDE HYDRATE N-甲基吗啉-N-氧化物一水合物 LABOTEST-BB LT00848163 N-Methylmorpholine N-oxide monohydrateNMMO nmmo Morpholine, 4-methyl-, 4-oxide, monohydrate 4-METHYLMORPHOLINE N-OXIDE MONOHYDRATE, 98+% 4-甲基吗啡-N-氧化物 一水合物 NMO monohydrate N-Methylmorpholine N-oxide monohydrate NMO 4-METHYLMORPHOLINE N-OXIDE MONOHYDRATE N-Methylmorpholine N-oxide monohydrat 4-METHYLMORPHOLINE-4-OXIDE MONOHYDRATE 97+% 4-甲基吗啉N氧化物单水合物 4-METHYLMORPHOLINE 4-OXIDE MONOHYDRATE {Chemicalbook |
| EC Number | 231-391-8 |
| CAS Number | 70187-32-5 |
| Beilstein Registry Number | 507437 |
| PubChem Substance ID | 57652112 |
| Chemical Name Translation | 4-甲基吗啡-N-氧化物一水合物 |
| InChIKey | WAZPLXZGZWWXDQ-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00196117 |
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分类
- {SNA} Building Blocks, C4 to C10, Chemical Synthesis, Heterocyclic Building Blocks, Morpholines/Thiomorpholines
产品应用
- 用于改进烯烃的催化 OsO4 氧化反应的试剂，该反应生成顺-1,2-二醇；用于醇的钌催化氧化反应，生成醛和酮
相关文献及参考
- Stoichiometric oxidant permitting the use of Osmium(VIII) oxide, 12103, catalytically in the cis-hydroxylation of alkenes: Tetrahedron Lett., 1973 (1976): Org. Synth. Coll., 6, 342 (1988). For use in the asymmetric dihydroxylation (ADH) reaction, catalyzed by Osmium(VIII) oxide, 12103, see: J. Am. Chem. Soc., 110, 1968 (1988); Org. Synth. Coll., 9, 383 (1998).
- In the presence of Ru catalysts such as RuCl3 or Dichlorotris(triphenylphosphine)ruthenium(II), L00373, oxidizes various types of alcohol to carbonyl compounds: Tetrahedron Lett., 2503 (1976). See also Tetra-n-propylammonium perruthenate(VII), B24511.
- In the presence of 4A molecular sieves in acetonitrile, activated (e.g. benzylic) halides can be oxidized to aldehydes and ketones: Synth. Commun., 22, 1967 (1992).
- Boronic esters formed by treatment of aryl bromides in THF with n-BuLi, followed by trimethyl borate, can be oxidized in situ to phenols without isolation of the boronic acid: Synlett, 931 (1995).
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- 下游产品:氢胺
- Acros Organics:4-甲基吗啉N氧化物单水合物 4-Methylmorpholine N-oxide monohydrate, 97%(70187-32-5)
- MOL 文件:70187-32-5.mol
- 用途一:主要作为纤维生产的纺丝溶剂，用于生产高档纤维、玻璃纸和植物性食物肠衣
- Sigma Aldrich:70187-32-5(sigmaaldrich)
- 上游原料:丙酮 --> 过氧化氢 --> 活性炭 --> 1,4-氧氮六环 --> N-甲基吗啡啉 --> 过一硫酸氢钾复合盐 --> N-甲基-N-氧化吗啉
- 敏感性:Hygroscopic
- Alfa Aesar:4-甲基吗啉-N-氧化物单水合物,98+% 4-Methylmorpholine N-oxide monohydrate, 98+%(70187-32-5)
- 氧化-4-甲基吗啉一水合物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 208341000 氧化-4-甲基吗啉一水合物 4-Methylmorpholine N-oxide monohydrate 97% 100 GR 2570元 2010/06/21 208340250 氧化-4-甲基吗啉一水合物 4-Methylmorpholine N-oxide monohydrate 97% 25 GR 713元 2010/05/25 A15996 4-甲基吗啉-N-氧化物单水合物, 98+% 4-Methylmorpholine N-oxide monohydrate, 98+% 10g 249元
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