Copper(II) acetate monohydrate, 98+%, extra pure 一水乙酸铜

CAS 6046-93-1 MFCD00149570

化学结构图

6046-93-1
SMILES: CC(=O)[O-].CC(=O)[O-].O.[Cu+2]

化学属性

Mol. FormulaC4H8CuO5
Mol. Weight199.65
Melting Point115 °C
Density1.882
TSCAYes
Vapor Density6.8 (vs air)
Appearance 一水物为蓝绿色粉末性结晶。 溶于乙醚。
Boiling Point240 °C at 760 mmHg
Solubility72 g/L (20 °C)
Stability对湿度敏感

别名和识别编码

Chemical NameCopper(II) acetate monohydrate, 98+%, extra pure
Synonym Copper(II)acetatemono hydrate {LY} Copper(II)acetatemono hydrate {} {LY} Copper(II)acetatemono hydrate {} {} {LY} Copper(II)acetatemono hydrate {} {} {} {LY} Copper(II)acetatemono hydrate {} {} {} {} {LY} Copper(II)acetatemono hydrate {} {} {} {} {} {LY} Copper(II)acetatemono hydrate {} {} {} {} {} {} {LY} Copper(II)acetatemono hydrate {} {} {} {} {} {} {} {LY} Copper(II)acetatemono hydrate {} {} {} {} {} {} {} {} {LY} Copper(II)acetatemono hydrate {} {} {} {} {} {} {} {} {} {LY} Copper(II)acetatemono hydrate {} {} {} {} {} {} {} {} {} {} {LY} Copper(II)acetatemono hydrate {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II)acetatemono hydrate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II)acetatemono hydrate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II)acetatemono hydrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II)acetatemono hydrate {} {} {} {} {} {} {} {} {}
CAS Number6046-93-1
PubChem Substance ID165397
EC Number205-553-3
Beilstein Registry Number3730548
MDL NumberMFCD00149570
Reaxys-RN3730548
Merck Number14,2624
Chemical Name Translation一水乙酸铜
Wiswesser Line NotationOV1 2 &-CU- &QH
LabNetwork Molecule IDLN00196854
InChIInChI=1S/2C2H4O2.Cu.H2O/c2*1-2(3)4;;/h2*1H3,(H,3,4);;1H2/q;;+2;/p-2
Canonical SMILES[Cu].O=C(O)C.O
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分类

  • {SNA} Copper, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper
  • Copper, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors

产品应用

  • 点滴分析钾和氰化物，松香的分析，作铜标准液，水质分析。

相关文献及参考

  • Promotes Ullmann-type C-O and C-N coupling reactions of arylboronic acids with phenols, amines and various other nitogen derivatives: Tetrahedron Lett., 39, 2933, 2937, 2941, 7979 (1998). Similar coupling reactions with thiols to give thioethers have also been reported: Org. Lett., 2, 2019 (2000).
  • Merck: 14,2624
  • Used in formation of Cu chelates of ß-dicarbonyl compounds as a means of purification, see, e.g.: Org. Synth. Coll., 3, 16, 292, 390 (1955).
  • Merck: 14,2624 Beilstein:2(4)94
  • For use in the Eglinton (modified Glaser) coupling of terminal alkynes, see: Org. Synth. Coll., 5, 517 (1973); for intramolecular example in the synthesis of [18]annulene, see: Org. Synth. Coll., 6, 68 (1988).
  • Useful catalyst for the Michael reaction giving increased yields and absence of side-reactions: Gazz. Chim. Ital., 114, 417 (1984).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes 9
RTECSAG3500000
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P317
  • P301+P330+P331
  • P302+P352
  • P302+P361+P354
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P316
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P317
  • P337+P317
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
UN Number 3077
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Packing GroupIII
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R50/53
Hazard Class9
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 710 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 5 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Gastrointestinal - changes in structure or function of salivary glands
   Gastrointestinal - nausea or vomiting
REFERENCE :
   JANSAG Journal of Animal Science.  (American Soc. of Animal Science, 309 W.
   Clark St., Champaign, IL 61820)  V.1-    1942-  Volume(issue)/page/year:
   55,337,1982

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 14,111,1985

其他信息

  • Acros Organics:乙酸铜单水合物 Copper(II) acetate monohydrate, extra pure, 98+%(6046-93-1)
  • 毒性分级:中毒
  • 上游原料:乙酸 --> 碳酸钠 --> 硫酸铜 --> 碱式碳酸铜
  • 灭火剂:水, 二氧化碳, 干粉, 砂土
  • 海关编码:29152900
  • 急性毒性:口服- 大鼠 LD50 710 毫克/ 公斤; 口服- 小鼠 LD50: 1600 毫克/公斤
  • 防护措施:本品有毒。操作人员应穿戴防护用具。
  • 储运特性:库房低温, 通风, 干燥 ; 与强氧化剂分开存放
  • TSCA:Yes
  • 用途一:用于印染、医药、油漆快干剂等
  • 类别:有毒物质
  • 下游产品:乙酰丙酮 --> 丙酸 --> 己二酸 --> 硫酸铜五水合物 --> 萘丁美酮 --> 4-叔丁基-6-三氟甲基-2-嘧啶胺 --> L-蛋氨酸 --> 二苯胍 --> 2-甲基巯基-4-氨基-6-甲基嘧啶 --> 4-氯-6-甲基-2-硫代甲基嘧啶 --> 联苯甲酰 --> 巴豆酸 --> DL-蛋氨酸 --> 8-羟基喹啉铜 --> 3-氟吡啶-2-羧酸 --> 2-硫代甲基-4-羟基-6-甲基嘧啶 --> 2-氢硫基-4-羟基-6-甲基嘧啶 --> 碘乙酸 --> 磷酸铜钙 --> 固色剂M --> 3,4-己二酮 --> 铜螯合物催化剂 --> 3-甲硫基丙醛 --> 硫酸奈替米星 --> 3-甲硫基丁醛 --> 酞菁素助剂 K
  • MOL 文件:6046-93-1.mol
  • 醋酸铜价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30044218 乙酸铜 500g 107元 2011/08/23 30044228 乙酸铜 500g 97元 2011/04/16 C2346 乙酸铜(II)单水合物 Copper(II) Acetate Monohydrate 25G 195元
  • 蒸气密度:6.9 (vs air)
  • 职业标准:TWA 1 毫克(铜)/立方米; STEL 2 毫克(铜)/立方米
  • 常规方法:试剂采用玻璃瓶或塑料袋装，工业品可用内衬塑料袋外加硬板桶包装。按一般化学品规定贮运。
  • 用途二:点滴分析钾和氰化物，松香的分析，作铜标准液，水质分析。
  • Alfa Aesar:乙酸铜(II),ACS,98.0-102.0% Copper(II) acetate monohydrate, ACS, 98.0-102.0%(6046-93-1)
  • 可燃性危险特性:可燃, 火场排出含铜辛辣刺激烟雾
  • MSDS 信息:Copper(II) acetate monohydrate(6046-93-1).msds
  • 在干燥空气中微有风化，有乙酸气味，能溶于水和醇，微溶于醚及甘油，240℃时脱去结晶水。
  • Sigma Aldrich:6046-93-1(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Copper Catalysis 铜催化剂
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Copper Catalysis 铜催化剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  5. C-D, Puriss p.a. ACS - Puriss p.a. ACS
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Copper - Solution Deposition Precursors
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  4. Cobalt
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Proteomics
  4. Post-Translational Modification
  5. Glycobiology
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Glycobiology
  4. Deglycosylation Strategies
  5. Chemical Deglycosylation
  6. Alkaline --elimination