Nickel(II) Nitrate Hexahydrate 硝酸镍(II)六水合物(易制爆)
CAS 13478-00-7 MFCD00149805
化学结构图
SMILES: O.O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Ni+2]
化学属性
| Mol. Formula | Ni(NO3)2· 6H2O |
|---|---|
| Mol. Weight | 290.79 |
| Density | 2.05 g/mL at 25 °C(lit.) |
| Melting Point | 56 °C(lit.) |
| Solubility | Soluble in water, alcohol |
| TSCA | Yes |
| Boiling Point | 137 |
| Flash Point | 137°C |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | Nickel(II) Nitrate Hexahydrate |
|---|---|
| CAS Number | 13478-00-7 |
| PubChem Substance ID | 61630 |
| EC Number | 236-068-5 |
| MDL Number | MFCD00149805 |
| Merck Number | 14,6513 |
| Synonym | 硝酸镍(II) 六水合物 硝酸镍 |
| Chemical Name Translation | 硝酸镍(II)六水合物(易制爆) |
| InChIKey | AOPCKOPZYFFEDA-UHFFFAOYSA-N |
| InChI | InChI=1S/2NO3.Ni.6H2O/c2*2-1(3)4;;;;;;;/h;;;6*1H2/q2*-1;+2;;;;;; |
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分类
- {SNA} Materials Science, Metal and Ceramic Science, Ni, Nickel Salts, Salts, Ultra-High Purity Materials
- {SA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, I-N, Puriss p.a., Puriss p.a.
- {SNA} Essential Chemicals, Metal and Ceramic Science, Ni, Nickel Salts, Research Essentials, Salts, Ultra-High Purity Materials, 材料科学
产品应用
- 用于镀镍、金属着色、镍催化剂、陶瓷褐色颜料、化学试剂等。
相关文献及参考
- Merck: 14,6513
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
- H350 May cause cancer 可能致癌
- H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H318 Causes serious eye damage 严重伤害眼睛
- H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
- H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
- H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
- H302+H332
- H332 Harmful if inhaled 吸入有害
- H302 Harmful if swallowed 吞食有害
- P305+P351+P338
- P273 Avoid release to the environment. 避免释放到环境中。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
- R38 Irritating to skin 刺激皮肤
- R49 May cause cancer by inhalation 吸入会致癌
- R42/43
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
- R48/23
- R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
- R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
- R50/53
- R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
其他信息
- 易溶于水、液氧、氨水、乙醇中，微溶于丙酮，水溶液呈酸性，PH值约为4。有吸湿性，潮湿空气中很快潮解。干燥空气中缓慢风化，受热时会失去四个分子水，温度高于110℃时开始分解并形成碱式盐，继续加热生成棕黑色的三氧化二镍和绿色的氧化亚镍的混合物。接触尘沫及其他有机物，有时能引起燃烧或爆炸。
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