Carbonylhydridotris(Triphenylphosphine)Rhodium(I) 三(三苯基膦)羰基氢化铑(I)

CAS 17185-29-4 MFCD00151644

化学结构图

17185-29-4
SMILES: [RhH].[C-]#[O+].C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1.C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1.C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC55H46OP3Rh
Mol. Weight919
Density1.33
SolubilitySoluble in hydrocarbons (e.g. benzene and toluene) with dissociation of phosphine ligands
TSCAYes
Melting Point150 °C (dec.)(lit.)

别名和识别编码

Chemical NameCarbonylhydridotris(Triphenylphosphine)Rhodium(I)
MDL NumberMFCD00151644
Synonym Carbonyltris(triphenylphosphine)rhodium(I) hydride RhH(CO)(PPh3)3 Rhodium monocarbonyl hydrogen tris(triphenylphosphine) Tris(triphenylphosphine)carbonylrhodium hydride trans-Carbonyl(hydrido)tris(triphenylphosphine)rhodium 羰基氢化三(三苯基磷)铑(I) 羰酰二氢三(三苯基膦)铑(I) Hydridocarbonyltris(triphenylphosphine)rhodium(I) 三(三苯基膦)羰基氢化铑 Tris(triphenylphosphine)rhodium carbonyl hydride
EC Number241-230-3
CAS Number17185-29-4
Merck Number9758
PubChem Substance ID87566394
Chemical Name Translation三(三苯基膦)羰基氢化铑(I)
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium

安全信息

Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
Storage condition Moisture Sensitive
WGK Germany1
GHS Symbol
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P302+P350
  • P301+P310
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P403+P233
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P304+P340+P311
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P301+P310+P330
  • P302+P352+P312+P361+P364
  • P405 Store locked up. 上锁保管。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Signal word Danger
Hazard statements
  • H301+H311+H331
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes T
UN Number 2811
Packing GroupIII
Hazard Class6.1

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Rhodium 铑
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Functional Group 官能团索引
  2. phosphine

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