3-(Trifluoromethyl)phenylboronic Acid 3-(三氟甲基)苯基硼酸

CAS 1423-26-3 MFCD00151854

化学结构图

1423-26-3
SMILES: OB(O)c1cccc(C(F)(F)F)c1

化学属性

Mol. FormulaC7H6BF3O2
Mol. Weight189.93
Melting Point163-166°C
TSCANo
Density1.36
Boiling Point268.2°C at 760 mmHg

别名和识别编码

Chemical Name3-(Trifluoromethyl)phenylboronic Acid
CAS Number1423-26-3
Alfabeta NameTRIFLUOROMETHYLPHENYLBORONICACID 3()-
MDL NumberMFCD00151854
Synonym 3-(Trifluoromethyl)phenylboronic acid {LY} 3-(Trifluoromethyl)phenylboronic acid {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {} {}
Beilstein Registry Number6084746
PubChem Substance ID2734388
Reaxys-RN6084746
EC Number000-000-0
Chemical Name Translation3-(三氟甲基)苯基硼酸
LabNetwork Molecule IDLN00004381
InChIInChI=1S/C7H6BF3O2/c9-7(10,11)5-2-1-3-6(4-5)8(12)13/h1-4,12-13H
Canonical SMILESFC(C1=CC(B(O)O)=CC=C1)(F)F
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分类

  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
  • {SA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
  • Aryl Boronic Acids,

相关文献及参考

  • 1. M. Ueda, et al., , Palladium-catalyzed cross-coupling reaction of N-alkoxyimidoyl bromides and its application to one-pot synthesis of N-arylamines Chem. Pharm. Bull. 59 , 1206-1208, (2011)
  • 2. T. Yasukawa, et al., , Copper-catalyzed, aerobic oxidative cross-coupling of alkynes with arylboronic acids: remarkable selectivity in 2,6-lutidine media Org. Biomolecular Chem. 9 , 6208-6210, (2011)
  • 3. M. Ayaz, et al., , A novel route to synthesize libraries of quinoxalines via Petasis methodology in two synthetic operations Tetrahedron Lett. 52 , 4821-4823, (2011)
  • 4. F. Xue, et al., , A Class of Benzene Backbone-Based Olefin-Sulfoxide Ligands for Rh-Catalyzed Enantioselective Addition of Arylboronic Acids to Enones J. Org. Chem. 76 , 7256-7262, (2011)
  • 5. F. Le Boucher d'Herouville, et al., , Room-temperature Rh-catalyzed asymmetric 1,4-addition of arylboronic acids to maleimides and enones in the presence of CF3-substituted MeOBIPHEP analogues J. Org. Chem. 76 , 6925-6930, (2011)
  • 6. G. R. Reddy, et al., , Pd-mediated new synthesis of pyrroles: their evaluation as potential inhibitors of phosphodiesterase 4 Chem. Commun. 47 , 7779-7781, (2011)
  • FT-IR 2 (3), 4463:B

安全信息

Warnings IRRITANT, KEEP COLD
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Hazard Codes Xi
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • Alfa Aesar:3-(三氟甲基)苯硼酸,98% 3-(Trifluoromethyl)benzeneboronic acid, 98%(1423-26-3)
  • Sigma Aldrich:1423-26-3(sigmaaldrich)
  • MOL 文件:1423-26-3.mol
  • Hazard Note:Irritant
  • TCI Shanghai:3-(三氟甲基)苯基硼酸(含有数量不等的酸酐) 3-(Trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride)(1423-26-3)
  • F:10-21
  • 3-(三氟甲基)苯硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1793 3-(三氟甲基)苯基硼酸(含有数量不等的酸酐) 3-(Trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 5G 340元 2014/06/02 T1793 3-(三氟甲基)苯基硼酸(含有数量不等的酸酐) 3-(Trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 1G 110元 2010/06/21 359750050 3-(三氟甲基)苯硼酸 3-Trifluoromethylphenylboronic acid 97+% 5 GR 2118元
  • Acros Organics:3-三氟甲基苯硼酸 3-Trifluoromethylphenylboronic acid, 97+%(1423-26-3)
  • 检测方法:HPLC,NMR

系列性分类


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