3-(Trifluoromethyl)phenylboronic acid 3-(三氟甲基)苯基硼酸

CAS 1423-26-3 MFCD00151854

化学结构图

1423-26-3
SMILES: OB(O)c1cccc(C(F)(F)F)c1

化学属性

Mol. FormulaC7H6BF3O2
Mol. Weight189.93
Melting Point163-166°C
TSCANo
Density1.36
Boiling Point268.2°C at 760 mmHg

别名和识别编码

Chemical Name3-(Trifluoromethyl)phenylboronic Acid
CAS Number1423-26-3
Alfabeta NameTRIFLUOROMETHYLPHENYLBORONICACID 3()-
MDL NumberMFCD00151854
Synonym 3-(Trifluoromethyl)phenylboronic acid {LY} 3-(Trifluoromethyl)phenylboronic acid CRTH2 antagonist CT-133 CT-133 {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylboronic
Beilstein Registry Number6084746
PubChem Substance ID2734388
Reaxys-RN6084746
EC Number000-000-0
Chemical Name Translation3-(三氟甲基)苯基硼酸
LabNetwork Molecule IDLN00004381
InChIInChI=1S/C7H6BF3O2/c9-7(10,11)5-2-1-3-6(4-5)8(12)13/h1-4,12-13H
Canonical SMILESFC(C1=CC(B(O)O)=CC=C1)(F)F
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分类

  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
  • {SA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
  • Aryl Boronic Acids,

相关文献及参考

  • 1. M. Ueda, et al., , Palladium-catalyzed cross-coupling reaction of N-alkoxyimidoyl bromides and its application to one-pot synthesis of N-arylamines Chem. Pharm. Bull. 59 , 1206-1208, (2011)
  • 2. T. Yasukawa, et al., , Copper-catalyzed, aerobic oxidative cross-coupling of alkynes with arylboronic acids: remarkable selectivity in 2,6-lutidine media Org. Biomolecular Chem. 9 , 6208-6210, (2011)
  • 3. M. Ayaz, et al., , A novel route to synthesize libraries of quinoxalines via Petasis methodology in two synthetic operations Tetrahedron Lett. 52 , 4821-4823, (2011)
  • 4. F. Xue, et al., , A Class of Benzene Backbone-Based Olefin-Sulfoxide Ligands for Rh-Catalyzed Enantioselective Addition of Arylboronic Acids to Enones J. Org. Chem. 76 , 7256-7262, (2011)
  • 5. F. Le Boucher d'Herouville, et al., , Room-temperature Rh-catalyzed asymmetric 1,4-addition of arylboronic acids to maleimides and enones in the presence of CF3-substituted MeOBIPHEP analogues J. Org. Chem. 76 , 6925-6930, (2011)
  • 6. G. R. Reddy, et al., , Pd-mediated new synthesis of pyrroles: their evaluation as potential inhibitors of phosphodiesterase 4 Chem. Commun. 47 , 7779-7781, (2011)
  • FT-IR 2 (3), 4463:B

安全信息

Warnings IRRITANT, KEEP COLD
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Hazard Codes Xi
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • Alfa Aesar:3-(三氟甲基)苯硼酸,98% 3-(Trifluoromethyl)benzeneboronic acid, 98%(1423-26-3)
  • Sigma Aldrich:1423-26-3(sigmaaldrich)
  • MOL 文件:1423-26-3.mol
  • Hazard Note:Irritant
  • TCI Shanghai:3-(三氟甲基)苯基硼酸(含有数量不等的酸酐) 3-(Trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride)(1423-26-3)
  • F:10-21
  • 3-(三氟甲基)苯硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1793 3-(三氟甲基)苯基硼酸(含有数量不等的酸酐) 3-(Trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 5G 340元 2014/06/02 T1793 3-(三氟甲基)苯基硼酸(含有数量不等的酸酐) 3-(Trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 1G 110元 2010/06/21 359750050 3-(三氟甲基)苯硼酸 3-Trifluoromethylphenylboronic acid 97+% 5 GR 2118元
  • Acros Organics:3-三氟甲基苯硼酸 3-Trifluoromethylphenylboronic acid, 97+%(1423-26-3)
  • 检测方法:HPLC,NMR

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DIA - DIC - D
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  6. Monosubstituted Aryl Boronic Acids - Aryl Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Alkyl
  1. Functional Group 官能团索引
  2. boronic acid

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