2-硝基苯基硼酸 2-硝基苯基硼酸
CAS 5570-19-4 MFCD00161358
化学结构图
SMILES: O=[N+]([O-])c1ccccc1B(O)O
化学属性
| Mol. Formula | C6H6BNO4 |
|---|---|
| Mol. Weight | 166.93 |
| Melting Point | 155-160°C |
| TSCA | No |
| Boiling Point | 374.7°C at 760 mmHg |
别名和识别编码
| Chemical Name | 2-硝基苯基硼酸 |
|---|---|
| Synonym | 2-Nitrophenylboronic acid {LY} 2-Nitrophenylboronic acid {} {LY} 2-Nitrophenylboronic acid {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {} {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {} {} {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {} {} {} {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Nitrophenylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
| MDL Number | MFCD00161358 |
| PubChem Substance ID | 2773548 |
| CAS Number | 5570-19-4 |
| Beilstein Registry Number | 3032097 |
| Chemical Name Translation | 2-硝基苯基硼酸 |
| Reaxys-RN | 3032097 |
| LabNetwork Molecule ID | LN00216886 |
| InChI | InChI=1S/C6H6BNO4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4,9-10H |
| Canonical SMILES | OB(C1=CC=CC=C1[N+]([O-])=O)O |
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分类
- {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
- Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
相关文献及参考
- 1. H. Zheng, et al., , Boronic acid catalysis for mild and selective [3+2] dipolar cycloadditions to unsaturated carboxylic acids Chem. Eur. J. 16 , 5454-5460, (2010)
- 2. H. Zheng, et al., , Mild and selective boronic acid catalyzed 1,3-transposition of allylic alcohols and Meyer-Schuster rearrangement of propargylic alcohols Chem. Sci. 2 , 1305-1310, (2011)
- 3. R. Zhong, et al., , Effect of counterions and central cores of tripodal imidazolium salts on palladium-catalyzed Suzuki-Miyaura cross-coupling reactions J. Organomet. Chem. 696 , 1703-1707, (2011)
- 4. J. T. Kuethe and K. G. Childers, , Suzuki-Miyaura cross-coupling of 2-nitroarenediazonium tetrafluoroborates: synthesis of unsymmetrical 2-nitrobiphenyls and highly functionalized carbazoles Adv. Synth. Catal. 350 , 1577-1586, (2008)
- 5. G. Zhang, et al., , Copper-catalyzed halogenation of arylboronic acids Tetrahedron Lett. 52 , 1993-1995, (2011)
- 6. P. Luo, et al., , Copper-catalyzed selective S-arylation of 1,2-bis(o-amino-1H-pyrazolyl) disulfides with arylboronic acids Synthesis 6 , 921-928, (2009)
- 7. J. Org. Chem. 70 , 9591, (2005) 摘要
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P301+P312+P330
- P302+P352
- P302+P352+P332+P313+P362+P364
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P330 Rinse mouth. 漱口
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H302 Harmful if swallowed 吞食有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- 2-硝基苯基硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0811 2-硝基苯硼酸(含有数量不等的酸酐) 2-Nitrophenylboronic Acid (contains varying amounts of Anhydride) 5G 1540元 2014/06/02 N0811 2-硝基苯硼酸(含有数量不等的酸酐) 2-Nitrophenylboronic Acid (contains varying amounts of Anhydride) 1G 435元 2010/05/25 L17988 2-硝基苯硼酸, 96% 2-Nitrobenzeneboronic acid, 96% 5g 2660元
- Alfa Aesar:2-硝基苯硼酸,96% 2-Nitrobenzeneboronic acid, 96%(5570-19-4)
- 上游原料:乙醚 --> 硫酸 --> 硝酸 --> 乙酐 --> 溴化苯基镁 --> 甲基硼酸
- Sigma Aldrich:5570-19-4(sigmaaldrich)
- TCI Shanghai:2-硝基苯基硼酸(含有数量不等的酸酐) 2-Nitrophenylboronic Acid (contains varying amounts of Anhydride)(5570-19-4)
- MOL 文件:5570-19-4.mol
- Hazard Note:Harmful
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