Methyl-5-Norbornene-2,3-Dicarboxylic Anhydride 甲基-5-降冰片烯-2,3-二羧酸酐

CAS 25134-21-8 MFCD00167036

化学结构图

25134-21-8
SMILES: CC1=C[C@@H]2C[C@H]1[C@H]1[C@@H]2C(=O)OC1=O |&1:3,5,6,7|

化学属性

Mol. FormulaC10H10O3
Mol. Weight178.19
Density1.232
Refractive index1.5050 to 1.5090
Flash Point135°C(lit.)
TSCAYes
Boiling Point140°C
Vapor Density6.1 (20 °C, vs air)
Vapor Pressure5 mmHg ( 120 °C)
Stability对湿度敏感

别名和识别编码

Chemical NameMethyl-5-Norbornene-2,3-Dicarboxylic Anhydride
MDL NumberMFCD00167036
Synonym 环氧树脂包埋剂，硬化剂 MNA 3-甲基内次甲基邻苯二甲酸酐 甲基-5-降冰片烯-2,3-二羧酸酐;3α,4,7,7α-四氢甲基-4,7-亚甲基异苯并呋喃-1,3-二酮;甲基-3.6-内次甲基四氢邻苯二甲酸酐;甲基内亚甲基四氢苯酐 甲基纳迪克酸酐 甲基内亚甲基四氢苯酐 Methyl nadic anhydride XMNA 甲基-5-降冰片烯-2,3-二羧酸酐 Epon™ MNA 替代品 MNA 甲基-5-降冰片烯-2,3-二羧酸酐 甲基纳迪克酸酐 甲基降冰片烯二酸酐 甲基-3.6-内次甲基四氢邻苯二甲酸酐
EC Number246-644-8
CAS Number25134-21-8
Beilstein Registry Number162395
PubChem Substance ID87572701
Chemical Name Translation甲基-5-降冰片烯-2,3-二羧酸酐
Wiswesser Line NotationL C555 A DVOV IUTJ X1
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Embedding Media, Embedding and Mounting Media, Microscopy Reagents
  • {SNA} Alicyclic/Etch-Resistant Monomers, Building Blocks, Carbonyl Compounds, Carboxylic Acid Anhydrides, Chemical Synthesis, Lithography Monomers, Micro/NanoElectronics, Organic Building Blocks, Self Assembly and Lithography, 材料科学
  • {SNA} Alicyclic/Etch-Resistant Monomers, Building Blocks, Carbonyl Compounds, Carboxylic Acid Anhydrides, Chemical Synthesis, Lithography Monomers,
  • {SNA} Alicyclic/Etch-Re
  • {SNA} Embedding Media, Embedding and Mounting Media, Microscopy Reagents, 分析/色谱, 分析试剂

产品应用

  • 在发电机、汽车用电机、变压器、转子等绝缘领域用作环氧树脂的固化剂、 FRP/FWP 等。

相关文献及参考

  • Beilstein: 17,V,11,199

安全信息

Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R42 May cause sensitisation by inhalation 吸入会产生过敏反应
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition Moisture Sensitive
Signal word
GHS Symbol
WGK Germany3
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P304+P340
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P304+P340+P310
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P301+P330+P331
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
RTECSRB9100000
Packing GroupIII
UN Number 3265
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
Hazard Codes C,Xn
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Class8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 914 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
   Washington, DC 20460)  History unknown.  Volume(issue)/page/year:
   8EHQ-0282-0431

其他信息

  • 和水反应。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Anhydrides 羧酸酐
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. B - Alphabetic
  5. BI - BZ - B
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Carboxylic Acid Anhydrides - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carbonates
  1. Functional Group 官能团索引
  2. carboxylic acid anhydride
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Microscopy Reagents
  4. Embedding and Mounting Media

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