5-Ethylidenebicyclo[2.2.1]Hept-2-Ene 5-亚乙基双环[2.2.1]庚烷-2-烯

CAS 16219-75-3 MFCD00167576

化学结构图

16219-75-3
SMILES: C/C=C1\C[C@@H]2C[C@H]\1C=C2 |&1:4,6|

化学属性

Mol. FormulaC9H12
Mol. Weight120
Refractive index1.4900 to 1.4920
Vapor Density4.1 (vs air)
Boiling Point146
Vapor Pressure4.6 mmHg ( 20 °C)
Density0.893
Flash Point38°C(lit.)
TSCAYes
Melting Point-80
Appearance 无色挥发性液体,有强烈的类樟脑气味。有顺、反两种异构体。顺式沸点147.35℃,反式沸点148.57℃,冰点-80℃,相对密度0.90(15/4℃),折光率1.4856(30℃),闪点38℃。有刺激性,易被氧化。贮存时用100ppm的对叔丁基邻苯二酚作为阴聚剂。

别名和识别编码

Chemical Name5-Ethylidenebicyclo[2.2.1]Hept-2-Ene
Synonym 5-Ethylidene-2-norbornene, mixture of endo and exo 5-Ethy ethylidenenorbornene (5E)-5-Ethylidenebicyclo[2.2.1]hept-2-ene 5-Ethylidene-2-norbornene {uni_hambu 2-norbornene, 5-ethylidene- 5-ethylidene- 5 mixcis+trans-5-ethylidenebicyclo[2.2.1]hept-2-ene 5-Ethylidene-2-norbornene, mixt. of 乙叉降冰生烯 5-Ethylidene bicyclo[2,2,1]heptene 5-乙叉-2-降冰片烯 bicyclo[2.2.1]hept-2-ene,5-ethylidene- 5-ethylidene-bicyclo(2.2.1)hept-2-en 5-ethylidene-2-norbornene,mixt.ofendo-andexo-isomers 5-ethylidene-8,9,10-trinorborn-2-ene 5-ethylidene-Bicyclo[2.2.1]hept-2-ene 5-亚乙基-2-降冰片烯, ENDO + EXO, 98%, 100PPM 对叔丁基儿 enb 5-ethylidenebicyclo(2.2.1)hept-2-ene 2-norbornene,5-ethylidene- Ethylidene norbornene 5-乙叉基双环[2,2,1]庚-2-烯 bicyclo[2.2.1]hept-2-ene, 5-ethylidene- mix cis + trans-5-ethylidenebicyclo[2.2.1]hept-2-ene 5-Ethylidenebicyclo[2,2,1]hept-2-nen 5-Ethylidenebicyclo(2.2.1)hept-2-ene 5-Ethylidenbicyclo(221)hept-2-en 5-ethylidenebicyclo(2,2,1)hep-2-ene ETHYLIDENE-2-NORBORNENE 5-乙缩醛-2-降莰烯 5-ethylidene-2-norbornene 2-Norbornene, 5-ethylidene-2-norbornen 5-Ethylidenebicyclo[2.2.1]-2-heptene 5-亚乙基降冰片烯-2 5-Ethyliden-2-norbornen, endo/exo Gemisch 5-亚乙基二环[2.2.1]庚-2-烯 5-Ethyliden-bicyclo[2.2.1]hept-2-en 亚乙基降冰片烯 5-Ethylidenebicyclo[2.2.1]hept-2-ene 5-ethylidene-b 乙叉降冰片烯 ETHYLIDENE NORBORNENE
PubChem Substance ID87569522
EC Number240-347-7
MDL NumberMFCD00167576
CAS Number16219-75-3
Chemical Name Translation5-亚乙基双环[2.2.1]庚烷-2-烯
Reaxys-RN2039936
Wiswesser Line NotationL55 A CY FUTJ CU2
Beilstein Registry Number2039935
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分类

  • {uni_hamburg} no charge; carbocycle; alicycle; fused rings; 5ring; 6ring; racemate; 1fragment
  • {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks
  • {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Materials Science, Monomers, Norbornene Monomers, Organic Building Blocks, Polymer Science
  • {SNA} Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Monomers, Norbornene Monomers, Organic Building Blocks, Polymer Science, 材料科学

相关文献及参考

  • Short: IV/18B Title: Viscosity of Pure Organic Liquids and Binary Liquid Mixtures: Pure Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: IV/18B Year: 2001 Keyword: organic compounds; viscosity; liquids; mixtures Internet Resource: DOI:10.1007/b68240 RefComment: VII, 409 pages.
  • Short: IV/20A Title: Vapor Pressure and Antoine Coefficients for Hydrocarbons and Sulfur-, Selenium-, Tellurium-, and Halogen-Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20A Year: 1999 Keyword: organic compounds; vapor pressure ISBN: 3-540-64735-X ISBN: 978-3-540-64735-5 Internet Resource: DOI:10.1007/b71086 RefComment: VIII, 373 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSRB9450000
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P303+P361+P353
  • P308+P313
  • P301+P310
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P337+P313
Signal word Danger
Safety Statements
Packing GroupIII
UN Number
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R10 Flammable 易燃
  • R20 Harmful by inhalation 吸入有害
Hazard Codes
Hazard Class3
Storage condition Flammables area
{haz

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2830 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 732 ppm/4H
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   20,250,1971

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 3104 ppm/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - ulcerated nasal septum
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   20,250,1971

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 6 ppm/30M
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Sense Organs and Special Senses (Eye) - conjunctive irritation
   Sense Organs and Special Senses (Taste) - change in function
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   20,250,1971

TYPE OF TEST

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 100 ppm/6H
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Maternal Effects - other effects
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   IOMTE3 International Journal of Occupational Medicine and Toxicology.
   (Princeton Scientific Publishing, POB 2155, Princeton, NJ 08543)  V.3(2)-
   4(4), 1994-95  Volume(issue)/page/year: 4,371,1995

其他信息

  • 蒸气压:4.6 mm Hg ( 20 °C)
  • Alfa Aesar:5-亚乙基-2-降冰片烯,endo+exo,98%,100ppm对叔丁基儿茶酚作稳定剂 5-Ethylidene-2-norbornene, endo + exo, 98%, stab. with 100ppm 4-tert-butylcatechol(16219-75-3)
  • 图谱信息:乙叉降冰生烯(16219-75-3)质谱(MS) 乙叉降冰生烯(16219-75-3)Raman光谱 乙叉降冰生烯(16219-75-3)红外图谱(IR1)
  • TCI Shanghai:5-乙叉-2-降冰片烯 5-Ethylidene-2-norbornene,>;98.0%(GC)(16219-75-3)
  • 方法一:用环戊二烯(或双环戊二烯)和1,3-丁二烯经第尔斯-阿尔德(Diels-Alder)反应得到乙烯基降冰片烯,再经异构化反应生成亚乙基降冰片烯。另一种制备法是以丁二烯为原料,经氯化制得3-氯-1-丁烯,再与歪戊二烯加成得5-(1-氯乙基)-2-降冰片烯,最后用氧化钙脱去盐酸而得产品。
  • Acros Organics:5-乙叉-2-降冰片烯 5-Ethylidene-2-norbornene, mixt. of endo- and exo-isomers, stabilized, 98+%(16219-75-3)
  • 用途一:该品作为第三单体,与乙烯、丙烯共聚可得乙丙橡胶。秘得橡胶的硫化速度比其他第三单体快,可以克服乙丙乙丙橡胶硫化速度慢的缺点。它还具有耐臭氧、耐化学药品(溶剂、酸、碱等)、耐放电、耐水蒸气等性能。因此,可用作发动机周围的橡胶制品、防水板等建筑材料和耐冲击性塑料的改性材料。
  • 乙叉降冰生烯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0244 5-亚乙基-2-降冰片烯 5-Ethylidene-2-norbornene 25ML 154元 2014/06/02 E0244 5-亚乙基-2-降冰片烯 5-Ethylidene-2-norbornene 500ML 530元 2010/06/21 166010025 乙叉降冰生烯 5-Ethylidene-2-norbornene 98+%, mixt. of endo- and exo-isomers, stabilized 2.5 KG 2223元
  • 上游原料:氧化钙 --> 1,3-丁二烯 --> 茂 --> 二聚环戊二烯 --> 降冰片烯 --> 3-氯-1-丁烯
  • MOL 文件:16219-75-3.mol
  • 蒸气密度:4.1 (vs air)
  • Sigma Aldrich:16219-75-3(sigmaaldrich)

系列性分类


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