9-Bbn Dimer 9-硼二环[3.3.1]壬烷二聚体

CAS 21205-91-4 MFCD00168069

化学结构图

21205-91-4
SMILES: C1C[C@H]2CCC[C@@H](C1)B2B1[C@H]2CCC[C@@H]1CCC2

化学属性

Mol. FormulaC16H30B2
Mol. Weight244
Melting Point150-152
TSCANo

别名和识别编码

Chemical Name9-Bbn Dimer
Synonym 9-BBN 9-硼双环[3.3.1]壬烷二聚物 9-Borabicyclo[3.3.1]nonane dimer 9-硼双环[3.3.1]壬烷二聚体
MDL NumberMFCD00168069
PubChem Substance ID24850763
Beilstein Registry Number 605509
CAS Number21205-91-4
Chemical Name Translation9-硼二环[3.3.1]壬烷二聚体
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分类

  • {SNA} Boranes, Chemical Synthesis, Reduction, Synthetic Reagents

相关文献及参考

  • Selective hydroborating agent. For use in hydroboration of terminal alkynes in the synthesis of long-chain alcohols, see: Tetrahedron, 48, 9187 (1992).
  • For a review of the chemistry of 9-BBN, see: Pure Appl. Chem., 63, 387 (1991); brief reviews of its uses in organic synthesis: J. Prakt. Chem./ Chem. Ztg., 338, 386 (1996); Synlett, 159 (2000).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P231+P232
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P422 Store contents under… 存储目录在…之下。
Hazard statements
  • H228 Flammable solid 易燃固体
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word Danger
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
Packing GroupII
UN Number 3396
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Air & Moisture Sensitive
Hazard Codes 4.3 F;Xi

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Potable- & Waste-Water Testing - Analytical Reagents
  4. Waste Water - Potable- & Waste-Water Testing
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Boranes - Reduction
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Boranes - Reduction

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