4-Piperidinemethanol 4-哌啶甲醇

CAS 6457-49-4 MFCD00174228

化学结构图

6457-49-4
SMILES: OCc1ccncc1

化学属性

Mol. FormulaC6H13NO
Mol. Weight115.17
Melting Point55-59°C
Density0.997
Flash Point110°C
TSCANo
Boiling Point118-120°C at 760 mmHg
Stability易吸潮

别名和识别编码

Chemical Name4-Piperidinemethanol
CAS Number6457-49-4
Alfabeta NamePIPERIDINEMETHANOL 4-
MDL NumberMFCD00174228
EC Number250-023-7
Beilstein Registry Number21(5)1,113
Synonym 4-Piperidinemethanol {LY} 4-Piperidinemethanol {} {LY} 4-Piperidinemethanol {} {} {LY} 4-Piperidinemethanol {} {} {} {LY} 4-Piperidinemethanol {} {} {} {} {LY} 4-Piperidinemethanol {} {} {} {} {} {LY} 4-Piperidinemethanol {} {} {} {} {} {} {LY} 4-Piperidinemethanol {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} 4-Piperidinemethanol {} {} {} {} {} {} {} {} {LY} 4-Piperidinemethanol {} {} {} {} {} {} {} {} {} {LY} 4-Piperidinemethanol {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 4-Piperidinemethanol {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Piperidinemethanol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Piperidinemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Piperidinemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Piperidinemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Piperidinemethanol {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID420771
Chemical Name Translation4-哌啶甲醇
Reaxys-RN103071
LabNetwork Molecule IDLN00007668
InChIInChI=1S/C6H13NO/c8-5-6-1-3-7-4-2-6/h6-8H,1-5H2
Canonical SMILESOCC1CCNCC1
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分类

  • {SNA} Building Blocks, C5 to C7, Chemical Synthesis, Heterocyclic Building Blocks, Piperidines

产品应用

  • 仲胺固相有机合成所用的底物。

相关文献及参考

  • Beilstein:21(5)1,113

安全信息

Warnings CORROSIVE
Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupII
UN Number
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes C C,Xi
Hazard Class8

其他信息

  • 用途一:用于有机合成
  • 下游产品:1-叔丁氧羰基-4-氨甲基哌啶 --> 特非那定 --> (1-(4-羟甲基-6-三氟甲基嘧啶-2-基)哌啶-4-基)甲醇 --> (2-(4-羟甲基哌啶-1-基)嘧啶-5-基)甲醇 --> 2-(4-羟甲基哌啶-1-基)-6-三氟甲基嘧啶-4-甲酰胺 --> 2-(4-羟甲基哌啶-1-基)嘧啶-5-甲酸 --> 4-(溴甲基)哌啶甲酸苄酯 --> 2-(4-羟甲基哌啶-1-基)嘧啶-5-甲酰胺 --> 2-(4-羟甲基哌啶-1-基)嘧啶-5-甲酸乙酯 --> 2-(4-氯甲基哌啶-1-基)嘧啶-5-甲酰胺 --> 2-(4-羟甲基哌啶-1-基)-6-三氟甲基嘧啶-4-甲酸乙酯 --> 1-叔丁氧羰基哌啶-4-甲醛
  • Sigma Aldrich:6457-49-4(sigmaaldrich)
  • Alfa Aesar:4-哌啶甲醇,98% 4-Piperidinemethanol, 98%(6457-49-4)
  • 4-羟甲基哌啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010220 4-哌啶甲醇 5g 450元 2011/04/16 P1653 4-哌啶甲醇 4-Piperidinemethanol 25G 2440元 2011/04/16 P1653 4-哌啶甲醇 4-Piperidinemethanol 5G 753元
  • Hazard Note:Irritant/Hygroscopic
  • Acros Organics:4-Piperidinemethanol, 98%(6457-49-4)
  • TCI Shanghai:4-哌啶甲醇 4-Piperidinemethanol,>;97.0%(GC)(T)(6457-49-4)
  • 敏感性:Hygroscopic
  • 用途二:用于固相第二位胺的有机合成中。
  • MOL 文件:6457-49-4.mol
  • 检测方法:GC,NMR

系列性分类


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