1-Tosylaziridine 1-对甲苯磺酰氮杂环丙烷

CAS 3634-89-7 MFCD00188412

化学结构图

3634-89-7
SMILES: Cc1ccc(S(=O)(=O)N2CC2)cc1

化学属性

Mol. FormulaC9H11NO2S
Mol. Weight197.25
Melting Point52-56 °C
Boiling Point322.3±35.0 °C at 760 mmHg

别名和识别编码

Chemical Name1-Tosylaziridine
CAS Number3634-89-7
Synonym 1-Tosylaziridine {LY} 1-Tosylaziridine {} {LY} 1-Tosylaziridine {} {} {LY} 1-Tosylaziridine {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {} {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {} {} {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylaziridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Tosylaziridine
MDL NumberMFCD00188412
Beilstein Registry Number154388
Chemical Name Translation1-对甲苯磺酰氮杂环丙烷
PubChem Substance ID561274
LabNetwork Molecule IDLN01097454
InChIInChI=1S/C9H11NO2S/c1-8-2-4-9(5-3-8)13(11,12)10-6-7-10/h2-5H,6-7H2,1H3
Canonical SMILESCC1=CC=C(S(N2CC2)(=O)=O)C=C1
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分类

  • {SNA} Aziridines, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • Aziridines, Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks

产品应用

  • Reagent for beta-aminoethylation as well as for chemical fixation of carbon dioxide via ring expansion reaction under atmospheric pressure.

相关文献及参考

  • Zollinger, J.L. et al.: J. Macromol. Sci Chem., 3, 1443 (1969); Sudo, A. et al.: Tetrahed. Lett., 45, 1363 (2004);
  • 1. Anet, F.A.L.,et. al. J. Am. Chem. Soc. 89 , 357, (1967)
  • 2. Garcia-Espana, E., et. al. Gazz. Chim. Ital. 115 , 399, (1985)

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Hazard Codes Xn
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Aziridines - Nitrogen Compounds

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