9,9-Bis(4-hydroxyphenyl)fluorene 双酚芴

CAS 3236-71-3 MFCD00191392

化学结构图

3236-71-3
SMILES: Oc1ccc(C2(c3ccc(O)cc3)c3ccccc3-c3ccccc32)cc1

化学属性

Mol. FormulaC25H18O2
Mol. Weight350.42
Melting Point224-226°C
Density1.288
Appearance 双酚芴为白色结晶粉末。熔点225-226℃。
Boiling Point526.4°C at 760 mmHg

别名和识别编码

Chemical Name9,9-Bis (4-Hydroxyphenyl) Fluorene
CAS Number3236-71-3
Alfabeta NameBISHYDROXYPHENYLFLUORENE 994()--,
MDL NumberMFCD00191392
Synonym 4,4'-(9H-Fluorene-9,9-diyl)diphenol {LY} 4,4'-(9H-Fluorene-9,9-diyl)diphenol 9,9-bis(4-hydroxyphenyl)fluorene fluorene-9-bisphenol {} {LY} 4,4'-(9H-Fluorene-9,9-diyl)diphenol {} {} {LY} 4,4'-(9H-Fluorene-9,9-diyl)diphenol {} {} {} {LY} 4,4'-(9H-Fluorene-9,9-diyl)diphenol {} {} {} {} {LY} 4,4'-(9H-Fluorene-9,9-diyl)diphenol {} {} {} {} {} {LY} 4,4'-(9H-Fluorene-9,9-diyl)diphenol {} {} {} {} {} {} {LY} 4,4'-(9H-Fluorene-9,9-diyl)diphenol {} {} {} {} {} {} {} {LY} 4,4'-(9H-Fluorene-9,9-diyl)diphenol {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 4,4'-(9H-Fluorene-9,9-diyl)diphenol {} {} {} {} {} {} {} {} {} {LY} 4,4'-(9H-Fluorene-9,9-diyl)diphenol {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-(9H-Fluorene-9,9-diyl)diphenol {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-(9H-Fluorene-9,9-diyl)diphenol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-(9H-Fluorene-9,9-diyl)diphenol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4,4'-(9H-Fluorene-9,9-diyl)di
PubChem Substance ID76716
Beilstein Registry Number2060986
EC Number406-950-6
Reaxys-RN2060986
Chemical Name Translation双酚芴
InChIKeyYWFPGFJLYRKYJZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00152759
Canonical SMILESOC1=CC=C(C=C1)C1(C2=CC=CC=C2C2=C1C=CC=C2)C1=CC=C(O)C=C1
InChIInChI=1S/C25H18O2/c26-19-13-9-17(10-14-19)25(18-11-15-20(27)16-12-18)23-7-3-1-5-21(23)22-6-2-4-8-24(22)25/h1-16,26-27H
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分类

  • {SNA} Bisphenol and Sulfonyldiphenol Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Bisphenol and Sulfonyldiphenol Monomers, Materials Science, Monomers, Polymer Science

产品应用

  • 用于合成新的聚亚芳基醚poly(arylene ethers)

相关文献及参考

  • 1. J. Polym. Sci., A: Polym. Chem. 29 , 1045, (1991)
  • FT-IR 2 (2), 1900:A / Structure Index 1 , 199:D:5

安全信息

Warnings IRRITANT
WGK Germany2
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Hazard Codes
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
UN Number 3077 UN 3077 9/PG 3
Safety Statements
Risk Statements
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R50/53
Packing GroupIII
Hazard Class9
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • MOL 文件:3236-71-3.mol
  • 功能性高分子材料的单体和改性剂:双酚芴是功能性高分子材料的单体和改性剂，是一种含有Cardo环骨架结构的双酚类化合物，是合成芴基环氧树脂、芴基苯并恶嗪树脂、丙烯酸酯树脂、聚酯树脂、聚碳酸酯、环氧树脂、聚酯或聚醚等缩聚产品的重要单体或改性剂。其中芴基环氧树脂具有优良的耐湿热性、介电性能、机械性能、耐化学品等综合性能，已成为高性能基体树脂材料、电子封装材料、耐高温胶黏剂、耐高温涂料等方面的重要单体与改性剂。但芴基环氧树脂的刚性较强，韧性差，因此，使用时需要对其进行增韧改性，或者是采用与通用环氧树脂共混的方式进行改性。
  • 双酚芴价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw01041660 双酚芴 25g 485元 2011/08/23 xw010416 双酚芴 5g 330元 2011/04/16 B1715 9,9-双(4-羟苯基)芴 9,9-Bis(4-hydroxyphenyl)fluorene 500G 6990元
  • 图谱信息:双酚芴(3236-71-3)质谱(MS)
  • Sigma Aldrich:3236-71-3(sigmaaldrich)
  • 用途一:用作有机合成中间体
  • 用途二:用于合成新的聚亚芳基醚poly(arylene ethers)
  • TCI Shanghai:9,9-二(4-羟苯基)芴 9,9-Bis(4-hydroxyphenyl)fluorene,>;98.0%(GC)(3236-71-3)

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. F - Alphabetic
  5. FA - FL - F
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Bisphenol and Sulfonyldiphenol Monomers - Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Fluorenes & Fluorenones
  1. Materials Science 材料科学
  2. Pressure & Heat Sensitive Recording Materials

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