Hexyllithium 正己基锂
CAS 21369-64-2 MFCD00191446
化学结构图
SMILES: [Li]CCCCCC
化学属性
| Mol. Formula | C6H13Li |
|---|---|
| Mol. Weight | 92.11 |
| Density | 0.708 |
| Flash Point | -26°(14°F) |
| TSCA | Yes |
| Boiling Point | 69 |
| Danger-Level | - |
| pH | -:- |
| Redox | - |
别名和识别编码
| Chemical Name | Hexyllithium |
|---|---|
| PubChem Substance ID | 24870524 |
| Beilstein Registry Number | 3600261 |
| MDL Number | MFCD00191446 |
| EC Number | 404-950-0 |
| CAS Number | 21369-64-2 |
| Synonym | n-Hexane, Hexyllithium solution |
| Chemical Name Translation | 正己基锂 |
| InChIKey | RMKNFFPDYCVCDI-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00163544 |
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分类
- {SA} Alkyl, Chemical Synthesis, Organic Bases, Organolithium, Organometallic Reagents, Synthetic Reagents
- {SNA} 25mL Sure/Seal Reagents, Alkyl, Chemical Synthesis, Organic Bases, Organolithium, Organometallic Reagents, Synthetic Reagents
- {SNA} 25mL Sure/Seal Reagents, Acids & Bases, Alkyl, Bases, Chemical Synthesis, Organic Bases, Organolithium, Organometallic Reagents, Synthetic Reagents
相关文献及参考
- Supplied in septum cap bottle.
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
- H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P222 Do not allow contact with air. 不要与空气接触。
- P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
- P231+P232
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
- R11 Highly flammable 非常易燃
- R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
- R17 Spontaneously flammable in air 在空气中能够自燃
- R35 Causes severe burns 会导致严重灼伤
- R48/20
- R51/53
- R62 Possible risk of impaired fertility 有削弱生殖能力的危险
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
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