Allyl 2-(Diethoxyphosphoryl)Acetate 2-(二乙氧基磷酰基)乙酸烯丙酯
CAS 113187-28-3 MFCD00191710
化学结构图
SMILES: CCOP(=O)(CC(=O)OCC=C)OCC
化学属性
| Mol. Formula | (C2H5O)2P(O)CH2COOCH2CH=CH2 |
|---|---|
| Mol. Weight | 236.20 |
| Refractive index | n20/D 1.445(lit.) |
| Boiling Point | 157-158 °C/10 mmHg(lit.) |
| Density | 1.12 g/mL at 25 °C(lit.) |
别名和识别编码
| Chemical Name | Allyl 2-(Diethoxyphosphoryl)Acetate |
|---|---|
| Synonym | P,P-二乙基膦酰基乙酸烯丙酯 膦酰基乙酸P,P-二乙基烯丙酯 |
| CAS Number | 113187-28-3 |
| PubChem Substance ID | 24865325 |
| Beilstein Registry Number | 1788582 |
| MDL Number | MFCD00191710 |
| Chemical Name Translation | 2-(二乙氧基磷酰基)乙酸烯丙酯 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents
相关文献及参考
- 1. Larivee, A.; et al. Angew. Chem. Int. Ed. Engl. 50 , 304, (2011)
- 2. Kedzia, J. L.; et al. Synlett , 649, (2010)
- 3. Lebreton, S.; et al. Bioorg. Med. Chem. Lett. 18 , 5879, (2008)
- 4. Bang, J. K.; et al. J. Org. Chem. 70 , 10596, (2005)
- 5. Aulenta, F.; et al. J. Org. Chem. 70 , 63, (2005)
- Beil. 4 ,IV,3610
- FT-IR 2 (1), 1567:B / Structure Index 1 , 171:A:8
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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