Azidotrimethyltin(IV) 三甲基甲硅烷基锡
CAS 1118-03-2 MFCD00191764
化学结构图
SMILES: C[Sn](C)(C)N=[N+]=[N-]
化学属性
| Mol. Formula | (CH3)3SnN3 |
|---|---|
| Mol. Weight | 208 |
| Melting Point | 117-120 °C(lit.) |
别名和识别编码
| Chemical Name | Azidotrimethyltin(IV) 97% |
|---|---|
| MDL Number | MFCD00191764 |
| PubChem Substance ID | 5104973 |
| CAS Number | 1118-03-2 |
| Synonym | Trimethylazidostannane 三甲基甲硅烷基锡 Trimethylstannyl azide Trimethyltin azide Tin, azidotrimethyl- 叠氮基三甲基锡 Azidotrimethylstannane Azidotrimethyltin Stannane, azidotrimethyl- |
| Chemical Name Translation | 三甲基甲硅烷基锡 |
| LabNetwork Molecule ID | LN01871723 |
| InChI | InChI=1S/3CH3.N3.Sn/c;;;1-3-2;/h3*1H3;;/q;;;-1;+1 |
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分类
- {uni_hamburg} no charge; metal-organic; 1fragment
- {SNA} Azide Sources, Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Organometallic Reagents, Organotin, Organotins
- {SNA} Azide Sources, Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Copper Click Chemistry, Organometallic Reagents, Organotin, Organotins
- Azide Sources, Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Organometallic Reagents, Organotin, Organotins
相关文献及参考
- Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
- Structure Index 1 , 486:A:1
安全信息
GHS Symbol
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P273 Avoid release to the environment. 避免释放到环境中。
- P301+P310
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- H330 Fatal if inhaled 吸入致命
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H310 Fatal in contact with skin 皮肤接触致命
- H300 Fatal if swallowed 吞食致命
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
- R50/53
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