(S,S)-2,2′-Isopropylidene-bis(4-phenyl-2-oxazoline) (S,S)-2,2'-异丙亚基-双(4-苯基-2-恶唑啉)

CAS 131457-46-0 MFCD00192245

化学结构图

131457-46-0
SMILES: CC(C)(C1=N[C@H](CO1)C1C=CC=CC=1)C1=N[C@H](CO1)C1C=CC=CC=1

化学属性

Mol. FormulaC21H22N2O2
Mol. Weight334
Density1.000
Boiling Point193
Melting Point37-41
Refractive index1.5620 to 1.5660

别名和识别编码

Chemical Name(S,S)-2,2′-Isopropylidene-bis(4-phenyl-2-oxazoline)
Synonym (-)-2,2′-异亚丙基双[(4S)-4-苯基-2-噁唑啉] (S,S)-2,2'-异亚丙基双(4-苯基-2-恶唑啉) (S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane (S,S)-2,2-双(4-苯基-2-噁唑啉-2-基)丙烷 (S,S)-2,2-双(4-苯基-2-噁唑啉-2-基)丙烷 (S,S)-2,2′-异亚丙基双(4-苯基-2-噁唑啉) (S,S)-2,2′-异亚丙基-双(4-苯基-2-噁唑啉) (S,S)-2,2′-异亚丙基双(4-苯基-2-噁唑啉)
MDL NumberMFCD00192245
PubChem Substance ID87571925
Beilstein Registry Number4266906
CAS Number131457-46-0
Reaxys-RN4266906
EC Number250-023-7
Chemical Name Translation(S,S)-2,2'-异丙亚基-双(4-苯基-2-恶唑啉)
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分类

  • Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
  • {SNA} Asymmetric Synthesis, BOX, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

相关文献及参考

  • 1. Gant, T.G. Meyers, A.I. Tetrahedron 50 , 2297, (1994)
  • 2. Pfaltz, A. Acc. Chem. Res. 26 , 339, (1993)
  • 3. Bolm, C. Angew. Chem. Int. Ed. Engl. 30 , 542, (1991)
  • FT-IR 2 (2), 2214:D / Structure Index 1 , 236:C:8

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Gloves
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 0-10°C

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Isoxazoles 异恶唑
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Oxazoles 恶唑
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Oxazolines/Oxazolidines 恶唑啉/恶唑烷
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BOX - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BOX - Privileged Ligands and Complexes

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