4-Nitrophenyl Trifluoromethanesulfonate 4-硝基苯三氟代甲烷

CAS 17763-80-3 MFCD00192354

化学结构图

17763-80-3
SMILES: O=[N+]([O-])c1ccc(OS(=O)(=O)C(F)(F)F)cc1

化学属性

Mol. FormulaC7H4F3NO5S
Mol. Weight271.17
Melting Point52.0 to 56.0 deg-C
TSCANo

别名和识别编码

Chemical Name4-Nitrophenyl Trifluoromethanesulfonate
CAS Number17763-80-3
Alfabeta NameNITROPHENYLTRIFLUOROMETHANESULFONATE %499-,
MDL NumberMFCD00192354
Synonym 4-硝基苯基三氟甲烷磺酸酯 4-Nitrophenyl triflate
PubChem Substance ID253662308
EC Number000-000-0
Beilstein Registry Number1998336
Chemical Name Translation4-硝基苯三氟代甲烷
Reaxys-RN1998336
LabNetwork Molecule IDLN00140485
InChIInChI=1S/C7H4F3NO5S/c8-7(9,10)17(14,15)16-6-3-1-5(2-4-6)11(12)13/h1-4H
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Triflates, Sulfur Compounds

相关文献及参考

  • FT-IR 2 (2), 3271:A / Structure Index 1 , 349:A:7
  • Stable, crystalline, non-hygroscopic triflating agent for phenols: Tetrahedron Lett., 38, 1181 (1997); and alcohols: J.Org.Chem., 64, 7638 (1999).

安全信息

Warnings KEEP COLD, TOXIC, CORROSIVE
WGK Germany3
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P312
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
Hazard Codes C
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
UN Number 3261
Risk Statements
Storage condition Moisture Sensitive
Packing GroupII
Hazard Class8

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitro Compounds 硝基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Organic Triflates - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Organic Triflates - Sulfur Compounds
  1. Functional Group 官能团索引
  2. sulfonic acid ester

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