(2-溴乙氧基)叔丁基二甲基硅烷 (2-溴乙氧基)叔丁基二甲基硅烷

CAS 86864-60-0 MFCD00209550

化学结构图

86864-60-0
SMILES: CC(C)(C)[Si](C)(C)OCCBr

化学属性

Mol. FormulaC8
Mol. Weight239
Boiling Point70-75
Refractive indexn20/D 1.444(lit.)
Density1.115

别名和识别编码

Chemical Name(2-溴乙氧基)叔丁基二甲基硅烷
CAS Number86864-60-0
Alfabeta NameBROMOETHOXYBUTYLDIMETHYLSILANE TERT2()---
MDL NumberMFCD00209550
Synonym (2-溴乙氧基)-叔丁基二甲基硅烷 {uni_hamburg} (2-bromoethoxy)-tert-butyldimethylsilane
PubChem Substance ID24866813
Chemical Name Translation(2-溴乙氧基)叔丁基二甲基硅烷
LabNetwork Molecule IDLN00010134
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Protected Alcohols/Phenols
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 用于 N-端 TBSO-乙基保护的试剂。用 Jones 试剂处理将发生水解并伴随着氧化反应生成N-乙酸,可进一步用于合成反应。
  • 用于钯催化 N-羟烷基化反应的有效试剂

相关文献及参考

  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 463 p. 40 illus., Hardcover RefComment: Written for: Scientists and engineers in the fields of physics, chemistry, and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment, i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 "Nuclear Magnetic Resonance (NMR) Data" is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 ''NMR-Data'' is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei B-11 and P-31, subvolume III/35B contains the nuclei F-19 and N-15, subvolume III/35C contains the nucleus H-1, subvolume III/35D contains the nucleus C-13, subvolume III/35E contains the nucleus O-17, subvolume III/35F contains the nucleus Si-29, and subvolume III/35G contains the nucleus Se-77. More nuclei will be presented later.

安全信息

Warnings IRRITANT
WGK Germany3
Hazard Codes Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
Signal word

系列性分类


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