(S)-8A-Methyl-3,4,8,8A-Tetrahydronaphthalene-1,6(2H,7H)-Dione (S)-8a-甲基-3,4,8,8a-四氢萘-1,6(2H,7H)-二酮
CAS 33878-99-8 MFCD00213797
化学结构图
SMILES: C[C@]12CCC(=O)C=C1CCCC2=O
化学属性
| Mol. Formula | C11H14O2 |
|---|---|
| Mol. Weight | 178 |
| Melting Point | 48-52° |
| TSCA | No |
别名和识别编码
| Chemical Name | (S)-8A-Methyl-3,4,8,8A-Tetrahydronaphthalene-1,6(2H,7H)-Dione |
|---|---|
| Synonym | (S)-Miescher-Wieland 酮 (S)-(+)-8a-甲基-3,4,8,8a-四氢-1,6(2H,7H)-萘二酮 (S)-(+)-9-Methyl-5(10)-octaline-1,6-dione Wieland-Miescher 酮 (S)-(+)-9-Methyl-ΔΔ55100-octalin-1,6-dione |
| MDL Number | MFCD00213797 |
| PubChem Substance ID | 24867341 |
| Beilstein Registry Number | 1569979 |
| CAS Number | 33878-99-8 |
| InChIKey | DNHDRUMZDHWHKG-UHFFFAOYSA-N |
| Chemical Name Translation | (S)-8a-甲基-3,4,8,8a-四氢萘-1,6(2H,7H)-二酮 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Ketones, Organic Building Blocks
相关文献及参考
- Key intermediate in enantioselective steroid syntheses; see, e.g.: Angew. Chem. Int. Ed., 10, 496 (1971); Chem. Ber., 106, 3636 (1973); J. Org. Chem., 45, 2204 (1980).
- For an example of use in synthesis of a diterpene, see: J. Chem. Soc., Perkin 1, 2151 (1986), and of taxane intermediates: J. Org. Chem., 57, 3274 (1992).
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