(S)-(-)-2,2-Bis(di-p-Tolylphosphino)-1,1-Binaphthyl (S)-(-)-2,2-双（二对甲苯基膦）-1,1-二联萘

CAS 100165-88-6 MFCD00269856

化学结构图

100165-88-6
SMILES: CC1C=C(C=CC=1)P(C1C=CC2C=CC=CC=2C=1C1=C(C=CC2C=CC=CC=21)P(C1=CC(C)=CC=C1)C1C=C(C)C=CC=1)C1C=C(C)C=CC=1

化学属性

TSCANo
Mol. FormulaC48H40P2
Mol. Weight679
Appearance white pwdr.
Melting Point255-257°C

别名和识别编码

Chemical Name(S)-(-)-2,2-Bis(di-p-Tolylphosphino)-1,1-Binaphthyl
Synonym (R)-Tol-BINAP (S)-(-)-2,2′-双(二-对甲苯基膦)-1,1′-联萘 (S)-Tol-BINAP (S)-Tol-BINAP (S)-(-)-2,2′-双(二对甲苯基膦)-1,1'-二联萘
Chemical Name Translation(S)-(-)-2,2-双（二对甲苯基膦）-1,1-二联萘
PubChem Substance ID329761556
Reaxys-RN5786041
MDL NumberMFCD01311709
CAS Number100165-88-6
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分类

  • {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINAPs - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes
  1. BINAP
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. BINAP
  2. 96-6950 Takasago BINAP Ligand Kit
  1. Ligands
  2. 96-6950 Takasago BINAP Ligand Kit
  1. Phosphine
  2. 96-6950 Takasago BINAP Ligand Kit

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