9-Phenanthrylmagnesium bromide 9-菲基溴化镁
CAS 71112-64-6 MFCD00672008
化学结构图
SMILES: Br[Mg]C1=CC2C=CC=CC=2C2C=CC=CC=21
化学属性
| Mol. Formula | C14H9BrMg |
|---|---|
| Mol. Weight | 281.43 |
| Density | 0.970 g/mL at 25 °C(lit.) |
| Boiling Point | 65 °C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | 9-Phenanthrylmagnesium bromide |
|---|---|
| MDL Number | MFCD00672008 |
| PubChem Substance ID | 24880126 |
| CAS Number | 71112-64-6 |
| Synonym | 9-菲基溴化镁 |
| Chemical Name Translation | 9-菲基溴化镁 |
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分类
- {SNA} Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
相关文献及参考
安全信息
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S39 Wear eye/face protection 戴眼睛/面孔保护装置；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S8 Keep container dry 保持容器干燥；
- R12 Extremely flammable 极端易燃
- R14 Reacts violently with water 遇水会猛烈反应
- R22 Harmful if swallowed 吞咽有害
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R34 Causes burns 会导致灼伤
- R11 Highly flammable 非常易燃
- R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P370+P378
- P403+P235
- P301+P312+P330
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