1,1’-Bis(Diphenylphosphino)Ferrocene-Palladium(II) Dichloride Dichloromethane Complex 1,1’-双(二苯膦基)二茂铁二氯化钯(II)二氯甲烷复合物

CAS 95464-05-4 MFCD00792899

化学结构图

95464-05-4
SMILES: ClCCl.Cl[Pd]Cl.[Fe].c1ccc(P(c2ccccc2)C2CCCC2)cc1.c1ccc(P(c2ccccc2)C2CCCC2)cc1

化学属性

Melting Point275-280°C
TSCANo
Mol. FormulaC35H30Cl4FeP2Pd
Appearance orange-red pwdr.
Mol. Weight816.64
RedoxReduction

别名和识别编码

Chemical Name1,1’-Bis(Diphenylphosphino)Ferrocene-Palladium(II) Dichloride Dichloromethane Complex
Alfabeta NameBISDIPHENYLPHOSPHINOFERROCENEPALLADIUMDICHLORIDEDICHLOROMETHANECOMPLEX II11(())---,'
Synonym Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct {LY} Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct {} {LY} Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct {} {} {LY} Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct {} {} {} {LY} Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct {} {} {} {} {LY} Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct {} {} {} {} {} {LY} Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct {} {} {} {} {} {} {LY} Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct {} {} {} {} {} {} {} {LY} Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct {} {} {} {} {} {} {} {} {LY} Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloromethane adduct
PubChem Substance ID24863679
Chemical Name Translation1,1’-双(二苯膦基)二茂铁二氯化钯(II)二氯甲烷复合物
LabNetwork Molecule IDLN01358290
MDL NumberMFCD00792899
CAS Number95464-05-4
Canonical SMILESClCCl.[][Fe][].Cl[Pd]([P](C1=CC=CC=C1)(C2=CC=CC=C2)c3cccc3)([P](C4=CC=CC=C4)(C5=CC=CC=C5)c6cccc6)Cl
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分类

  • {SNA} Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Development Quantities for Research, Homogeneous Pd Catalysts, Palladium
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium
  • {SA} ChemDose, Chemical Synthesis, Specialty Synthesis
  • {SNA} Catalysis,

相关文献及参考

  • Preferred catalyst for coupling of aryl halides and triflates to give arylamines or aryl ethers. For a review, see: Angew. Chem. Int. Ed., 37, 2046 (1998). Catalyst for boronylation reactions with Bis(pinacolato)­diboron, L16088: J. Org. Chem., 60, 7508 (1995).

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352+P312+P362+P364
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H302+H312+H332
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H351 Suspected of causing cancer 怀疑致癌
Signal word Warning
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R48/20/22
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Hazard Codes Xn
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

系列性分类

  1. Chemical Synthesis 化学合成
  2. Specialty Synthesis 特殊合成技术
  3. ChemDose™ - Specialty Synthesis
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Palladium Catalysis 钯催化剂
  4. Homogeneous Pd Catalysts - Palladium
  1. Catalysts
  2. Palladium
  1. Metallocenes, Derivatives & Cp Precursors
  2. Palladium
  1. Catalysts
  2. 96-3735 [1,1'-Bis(dialkyl/diarylphosphino)ferrocene]palladium(II) dichcloro Catalyst Kit
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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