(-)-1,2-Bis[(2S,5S)-2,5-diethyl-1-phospholanyl]ethane (-)-1,2-双[(2S,5S)-2,5-二乙基-1-亚磷基]乙烷

CAS 136779-27-6 MFCD01073769

化学结构图

136779-27-6
SMILES: CC[C@H]1CC[C@H](CC)P1CCP1[C@H](CC[C@@H]1CC)CC

化学属性

Refractive indexn20/D 1.5243
Mol. Formula(C8H16)PCH2CH2P(C8H16)
Mol. Weight314
Appearance colorless to pale-yellow liq.
Stabilityair sensitive
Boiling Point104-106°C/0.05mm

别名和识别编码

Chemical Name(-)-1,2-Bis[(2S,5S)-2,5-diethyl-1-phospholanyl]ethane
Synonym (-)-1,2-双[(2S,5S)-2,5-二乙基膦烷基]乙烷 (S,S)-Et-BPE
PubChem Substance ID24884984
Chemical Name Translation(-)-1,2-双[(2S,5S)-2,5-二乙基-1-亚磷基]乙烷
MDL NumberMFCD01073769
CAS Number136779-27-6
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes

安全信息

Hazard Codes F
WGK Germany3
GHS Symbol
Precautionary statements
  • P222 Do not allow contact with air. 不要与空气接触。
  • P422 Store contents under… 存储目录在…之下。
  • P231 Handle under inert gas. 在惰性气体中操作。
Signal word Danger
Hazard statements
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Safety Statements
  • S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中；
Risk Statements
  • R17 Spontaneously flammable in air 在空气中能够自燃

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. DuPhos/BPE - Privileged Ligands and Complexes
  1. Functional Group 官能团索引
  2. phosphine
  1. BPE
  2. Phosphorus
  1. DUPHOS
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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