1,2-Bis[(2S,5S)-2,5-Dimethyl-1-Phospholanyl]Ethane 1,2-双[(2S,5S)-2,5-二甲基-1-亚磷基]乙烷

CAS 136779-26-5 MFCD01073771

化学结构图

136779-26-5
SMILES: C[C@H]1CC[C@H](C)P1CCP1[C@@H](C)CC[C@@H]1C

化学属性

Mol. FormulaC14H28P2
Mol. Weight258.32
Density0.938 g/mL at 25 °C
Boiling Point64-67 °C/0.06 mmHg
Refractive indexn20/D 1.535
Appearance colorless to pale-yellow liq.
Stabilityair sensitive

别名和识别编码

Chemical Name1,2-Bis[(2S,5S)-2,5-Dimethyl-1-Phospholanyl]Ethane
Synonym (-)-1,2-双[(2S,5S)-2,5-二甲基磷]乙烷 (S,S)-Me-BPE
MDL NumberMFCD01073771
PubChem Substance ID24884722
CAS Number136779-26-5
Chemical Name Translation1,2-双[(2S,5S)-2,5-二甲基-1-亚磷基]乙烷
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes

相关文献及参考

安全信息

WGK Germany3
Precautionary statements
  • P222 Do not allow contact with air. 不要与空气接触。
  • P422 Store contents under… 存储目录在…之下。
  • P231 Handle under inert gas. 在惰性气体中操作。
Signal word Danger
Hazard statements
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
Hazard Codes F
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Risk Statements
  • R17 Spontaneously flammable in air 在空气中能够自燃

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. DuPhos/BPE - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. DuPhos/BPE - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes
  5. DIPAMP
  1. Functional Group 官能团索引
  2. phosphine
  1. BPE
  2. Phosphorus
  1. DUPHOS
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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