2,3-Dichlorophenylboronic Acid 2,3-二氯苯硼酸

CAS 151169-74-3 MFCD01075703

化学结构图

151169-74-3
SMILES: OB(O)C1C=CC=C(Cl)C=1Cl

化学属性

Mol. FormulaC6H5BCl2O2
Mol. Weight191
Melting Point242-244
TSCANo
Density1.47

别名和识别编码

Chemical Name2,3-Dichlorophenylboronic Acid
CAS Number151169-74-3
Alfabeta NameDICHLOROPHENYLBORONICACID 23-,
MDL NumberMFCD01075703
Synonym (2,3-Dichlorophenyl)dihydroxyborane (2,3-Dichlorophenyl)dihydroxyborane 2,3-Dichlorobenzeneboronic acid 2,3-Dichlorobenzeneboronic acid
PubChem Substance ID87559733
Reaxys-RN9552248
EC Number000-000-0
Beilstein Registry Number2384789
Chemical Name Translation2,3-二氯苯硼酸
LabNetwork Molecule IDLN00120772
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分类

  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. Rodriguez-Aristegui, S.; et al., Versatile synthesis of functionalised dibenzothiophenes via Suzuki coupling and microwave-assisted ring closure Org. Biomolecular Chem. 9 , 6066-6074, (2011)
  • 2. Thornton, P. D.; et al., Application of 6,7-Indole Aryne Cycloaddition and Pd(0)-Catalyzed Suzuki-Miyaura and Buchwald-Hartwig Cross-Coupling Reactions for the Preparation of Annulated Indole Libraries ACS Comb. Sci. 13 , 443-448, (2011)
  • 3. Gollner, A.; Koutentis, P. A. , Two-Step Total Syntheses of Canthin-6-one Alkaloids: New One-Pot Sequential Pd-Catalyzed Suzuki-Miyaura Coupling and Cu-Catalyzed Amidation Reaction Org. Lett. 12 , 1352-1355, (2010)
  • 4. Tyagarajan, S.; et al., Discovery of a novel class of biphenyl pyrazole sodium channel blockers for treatment of neuropathic pain Bioorg. Med. Chem. Lett. 20 , 7479-7482, (2010)

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. E - Alphabetic
  5. EQ - EZ - E
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  6. Disubstituted Aryl Boronic Acids - Aryl Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Alkyl
  1. Functional Group 官能团索引
  2. boronic acid

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