Α-Methylbenzylzincchloride α-甲基苄基溴化锌

CAS 85459-20-7 MFCD01311436

化学结构图

85459-20-7
SMILES: CC([Zn]Br)C1C=CC=CC=1

化学属性

Mol. FormulaC6H5CH(CH3)ZnBr
Mol. Weight250.45
Density0.965
TSCANo

别名和识别编码

Chemical NameΑ-Methylbenzylzincchloride
MDL NumberMFCD01311436
PubChem Substance ID24873224
Synonym α-甲基苯甲基溴化锌 溶液
CAS Number85459-20-7
Chemical Name Translationα-甲基苄基溴化锌
EC Number203-726-8
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分类

  • {SNA} Alkyl, Chemical Synthesis, Organometallic Reagents, Organozinc Halides, Rieke and Organozinc Reagents

安全信息

WGK Germany3
Hazard Codes
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Risk Statements
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R14 Reacts violently with water 遇水会猛烈反应
  • R22 Harmful if swallowed 吞咽有害
Packing GroupII
UN Number
Storage condition Air Sensitive
Precautionary statements
  • P402+P404
  • P231+P232
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P370+P378
  • P403+P235
Signal word
GHS Symbol
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organozinc Reagents 有机锌试剂
  4. Organozinc Halides 有机锌卤化物
  5. Alkyl - Organozinc Halides
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organozinc Reagents 有机锌试剂
  4. Organozinc Halides 有机锌卤化物
  5. Alkyl - Organozinc Halides

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