4-(Bromomethyl)phenylboronic acid 4-(溴甲基)苯硼酸
CAS 68162-47-0 MFCD01318113
化学结构图
SMILES: OB(O)C1C=CC(CBr)=CC=1
化学属性
| Mol. Formula | C7 |
|---|---|
| Mol. Weight | 215 |
| Melting Point | 165-172 |
| TSCA | No |
别名和识别编码
| Chemical Name | 4-(Bromomethyl)phenylboronic acid |
|---|---|
| CAS Number | 68162-47-0 |
| Alfabeta Name | BROMOMETHYLPHENYLBORONICACID 4()- |
| MDL Number | MFCD01318113 |
| Synonym | α-Bromo-p-tolueneboronic acid p-Boronobenzyl bromide α-Bromo-p-tolueneboronic acid 4-Boronobenzyl bromide p-Boronobenzyl bromide α-Bromo-p-tolueneboronic acid 4-(溴甲基)苯硼酸 |
| PubChem Substance ID | 24885493 |
| Beilstein Registry Number | 3030979 |
| Chemical Name Translation | 4-(溴甲基)苯硼酸 |
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分类
- {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
- Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
相关文献及参考
- 1. H. M. H. G. Albers, et al., , Structure-Based Design of Novel Boronic Acid-Based Inhibitors of Autotaxin J. Med. Chem. 54 , 4619-4626, (2011)
- 2. D. E. Morrison, et al., , Boronated phosphonium salts containing arylboronic acid, closo-carborane, or nido-carborane: synthesis, x-ray diffraction, in vitro cytotoxicity, and cellular uptake J. Biol. Inorg. Chem. 15 , 1305-1318, (2010)
- 3. S. Gamsey, et al., , The effect of boronic acid-positioning in an optical glucose-sensing ensemble Tetrahedron 62 , 6321-6331, (2006)
- Q. Peng, et al., , Enhanced gene transfection capability of polyethylenimine by incorporating boronic acid groups Chem. Commun. 46 , 5888-5890, (2010)
- Has been employed in the synthesis of para-substituted boronated stilbenes via the Wittig reaction: J. Am. Chem. Soc., 117, 8982 (1995), which were subsequently employed as highly selective fluorescent probes for glucose: J. Phys. Chem. A, 105, 6834 (2001).
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312
- P302+P352
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H302 Harmful if swallowed 吞食有害
- H319 Causes serious eye irritation 严重刺激眼睛
- S22 Do not breathe dust 不要吸入粉尘；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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