(6-Formylbenzo[D][1,3]Dioxol-5-Yl)Boronic Acid (6-甲酰基苯并[d][1,3]二氧杂环戊烯-5-基)硼酸

CAS 94838-88-7 MFCD01319005

化学结构图

94838-88-7
SMILES: OB(O)C1C=C2OCOC2=CC=1C=O

化学属性

Mol. FormulaC8H7BO5
Mol. Weight194
Melting Point231-233°
TSCANo

别名和识别编码

Chemical Name(6-Formylbenzo[D][1,3]Dioxol-5-Yl)Boronic Acid
MDL NumberMFCD01319005
CAS Number94838-88-7
Chemical Name Translation(6-甲酰基苯并[d][1,3]二氧杂环戊烯-5-基)硼酸
Synonym (2-甲酰基-4,5-亚甲二氧基)苯基硼酸
PubChem Substance ID329763508
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分类

  • Aldehydes, Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Building Blocks, C8, Carbonyl Compounds, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organic Building Blocks, Organometallic Reagents
  • {SNA} Aldehydes, Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Building Blocks, C8, Carbonyl Compounds, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organic Building Blocks, Organometallic Reagents

相关文献及参考

  • 1. Yu, X.; Lu, X., Cationic Palladium Complex-Catalyzed Diastereoselective Tandem Annulation of 2-Iminoarylboronic Acids with Substituted Alkynes: Enantioselective Synthesis of Aminoindene Derivatives by Double Asymmetric Induction Adv. Synth. Catal. 353 , 2805-2813, (2011)
  • 2. Yu, X.; Lu, X., Cationic Palladium Complex Catalyzed Diastereo- and Enantioselective Tandem Annulation of 2-Formylarylboronic Acids with Allenoates Org. Lett. 11 , 4366-4369, (2009)
  • 3. Molander, G. A.; et al., Condensation Reactions To Form Oxazoline-Substituted Potassium Organotrifluoroborates Org. Lett. 11 , 3830-3833, (2009)
  • 4. Choi, Y. L.; et al., Synthesis of aristolactam analogues and evaluation of their antitumor activity Bioorg. Med. Chem. Lett. 19 , 3036-3040, (2009)
  • 5. Choi, Y. L.; et al., Efficient Synthesis of Dibenzo[a,c]cyclohepten-5-ones via a Sequential Suzuki-Miyaura Coupling and Aldol Condensation Reaction J. Org. Chem. 74 , 3948-3951, (2009)
  • 6. Mamane, V.; et al., A general and efficient method for the synthesis of benzo-(iso)quinoline derivatives Tetrahedron 64 , 10699-10705, (2008)

安全信息

GHS Symbol
WGK Germany2
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes Xi

系列性分类


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