3-Iodophenylboronic Acid 3-碘苯硼酸

CAS 221037-98-5 MFCD01319015

化学结构图

221037-98-5
SMILES: OB(O)C1C=C(I)C=CC=1

化学属性

Mol. FormulaC6H6BIO2
Mol. Weight248
Melting Point195-197
TSCANo
Density1.422

别名和识别编码

Chemical Name3-Iodophenylboronic Acid
CAS Number221037-98-5
Alfabeta NameIODOPHENYLBORONICACID 3-
MDL NumberMFCD01319015
PubChem Substance ID24867695
Synonym 3-碘苯硼酸 3-Iodophenylboronic acid
EC Number250-023-7
Beilstein Registry Number2384789
Chemical Name Translation3-碘苯硼酸
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分类

  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. H. Li, et al., , Ru-catalyzed aerobic oxidative coupling of arylboronic acids with arenes Chem. Commun. 47 , 1497-1499, (2011)
  • 2. T. A. Mitchell and J. W. Bode, , Synthesis of Dialkyl Ethers from Organotrifluoroborates and Acetals J. Am. Chem. Soc. 131 , 18057-18059, (2009)
  • 3. T. G. Elford, et al., , Diversity-Oriented Synthesis and Preliminary Biological Screening of Highly Substituted Five-Membered Lactones and Lactams Originating From an Allylboration of Aldehydes and Imines J. Comb. Chem. 11 , 155-168, (2009)
  • 4. J. O'Neill, et al., , Chemoselective three-component coupling via a tandem Pd-catalyzed boron-Heck and Suzuki reactions Tetrahedron Lett. 49 , 7307-7310, (2008)
  • 5. H. M. Hugel, et al., , Comparison of copper(II) acetate promoted N-arylation of 5,5-dimethylhydantoin and other imides with triarylbismuthanes and arylboronic acids Synlett 14 , 2290-2292, (2006)
  • 6. E. J. Farrington, et al., , Ruthenium complex-catalyzed Heck reactions of areneboronic acids; mechanism, synthesis and halide tolerance Adv. Synth. Catal. 347 , 185-195, (2005)
  • Beil. 16 ,IV,1669

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Light Sensitive

系列性分类


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