(R,R)-iPr-Pybox (R,R)-2,6-双(4-异丙基-2-噁唑啉-2-基)吡啶

CAS 131864-67-0 MFCD01321334

化学结构图

131864-67-0
SMILES: CC(C)[C@@H]1COC(=N1)C1=CC=CC(=N1)C1=N[C@@H](CO1)C(C)C

化学属性

Mol. FormulaC17H23N3O2
Mol. Weight301
Appearance white xtl. white-light yellow pwdr.
Melting Point152-153°C
Stabilitystore cold

别名和识别编码

Chemical Name(R,R)-iPr-Pybox
Alfabeta NameBISISOPROPYLDIHYDROOXAZOLYLPYRIDINE R264452(())--------,,
PubChem Substance ID87565072
Reaxys-RN15421598
Synonym 2,6-双[(4R)-(+)-异丙基-2-噁唑啉-2-基]吡啶
Chemical Name Translation(R,R)-2,6-双(4-异丙基-2-噁唑啉-2-基)吡啶
Beilstein Registry Number15421598
MDL NumberMFCD01321334
CAS Number131864-67-0
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, PyBOX
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, PyBOX

相关文献及参考

  • 1. Gant, T.G. Meyers, A.I. Tetrahedron 50 , 2297, (1994)
  • 2. Pfaltz, A. Acc. Chem. Res. 26 , 339, (1993)
  • 3. Bolm, C. Angew. Chem. Int. Ed. Engl. 30 , 542, (1991)

安全信息

Warnings IRRITANT
WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Storage condition 0-10 0-10°C
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Heterocyclic Building Blocks - Chiral Building Blocks
  5. Oxazoles - Heterocyclic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. PyBOX - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. PyBOX - Privileged Ligands and Complexes
  1. Functional Group 官能团索引
  2. imido ester
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶
  1. Pybox
  2. Nitrogen
  1. Ligands
  2. Nitrogen
  1. Pincer Ligands and Complexes
  2. Nitrogen

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