1,1’-Bis(Dichlorophosphino)Ferrocene 1,1’-双(二氯膦基)二茂铁

CAS 142691-70-1 MFCD01630854

化学结构图

142691-70-1
SMILES: [Fe].ClP(Cl)[C]1[CH][CH][CH][CH]1.ClP(Cl)[C]1[CH][CH][CH][CH]1 |^1:4,5,6,7,8,12,13,14,15,16|

化学属性

Mol. FormulaC10H8Cl4FeP2
Mol. Weight387.77
Melting Point68.0 to 72.0 deg-C
TSCANo
Appearance yellow pwdr.
Stabilitymoisture sensitive

别名和识别编码

Chemical Name1,1’-Bis(Dichlorophosphino)Ferrocene
MDL NumberMFCD01630854
CAS Number142691-70-1
Synonym 1,1′-双(二氯磷)二茂铁
Chemical Name Translation1,1’-双(二氯膦基)二茂铁
PubChem Substance ID253662299
Reaxys-RN16776000
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Catalysts for Polymerization, Chemical Synthesis, Materials Science, Olefin Polymerization, Phosphine Compounds, Phosphorus Precursors, Polymer Science, Reagents for Polymerization
  • {SNA} Catalysis and Inorganic Chemistry, Catalysts for Polymerization, Chemical Synthesis, Olefin Polymerization, Phosphine Compounds, Phosphorus Precursors, Polymer Science, Reagents for Polymerization, 材料科学

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Signal word Danger
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing GroupII
UN Number 3261 UN3261
Risk Statements
  • R34 Causes burns 会导致灼伤
Storage condition Moisture Sensitive
Hazard Codes C
Hazard Class8

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphorus Precursors - Phosphorus Compounds
  1. Phosphine
  2. Iron
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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