(1R,2R)-N,N’-(Cyclohexane-1,2-Diyl)Bis(2-(DiphenylPhosphino)Benzamide) (1R,2R)-N,N-双(2-二苯基膦基苯甲酰)-1,2-环己二胺

CAS 138517-61-0 MFCD01631273

化学结构图

138517-61-0
SMILES: O=C(N[C@@H]1CCCC[C@H]1NC(=O)C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1)C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC44H40N2O2P2
Mol. Weight690.75
Melting Point136-142 °C
StabilityPneumatic operation and storage
Appearance white to off-white pwdr.

别名和识别编码

Chemical Name(1R,2R)-N,N’-(Cyclohexane-1,2-Diyl)Bis(2-(DiphenylPhosphino)Benzamide)
Synonym (R,R)-DACH-苯基 Trost 配体 N′-双(2-二苯基磷苯甲酰) (1R 2-二氨基环己烷-N (1R,2R)-(+)-1,2-二氨基环己烷-N,N′-双(2-二苯基磷苯甲酰) 2R)-(+)-1
MDL NumberMFCD01631273
CAS Number138517-61-0
Chemical Name Translation(1R,2R)-N,N-双(2-二苯基膦基苯甲酰)-1,2-环己二胺
PubChem Substance ID329761529
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Trost Ligands
  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Trost Ligands

相关文献及参考

  • 1. Trost, B.M. et al. Chem. Rev. 96 , 395, (1996) 摘要
  • 2. Trost, B.M. et al. Chem. Rev. 103 , 2921, (2003) 摘要
  • 3. Trost, B.M. et al. J. Am. Chem. Soc. 124 , 11616, (2004)
  • 4. Trost, B.M. et al. Aldrichimica Acta 40 , 59, (2007)

安全信息

WGK Germany3

其他信息

  • 不对称烯丙基烷化反应的配体.

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. Trost Ligands - Privileged Ligands and Complexes
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Phosphorus
  1. TROST
  2. Phosphorus
  1. Ligands
  2. Phosphorus

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