N,N''-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide] N,N''-(1S,2S)-1,2-环己烷二基双[2-(二苯基膦基)苯甲酰胺]

CAS 169689-05-8 MFCD01631274

化学结构图

169689-05-8
SMILES: O=C(N[C@H]1CCCC[C@@H]1NC(=O)C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1)C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. FormulaC44H40N2O2P2
Mol. Weight690.75
Melting Point136-142 °C
Appearance white to off-white pwdr.

别名和识别编码

Chemical NameN,N''-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide]
Synonym (S,S)-DACH-苯基 Trost 配体 (1S,2S)-(–)-1,2-二氨基环己烷-N,N′-双(2-二苯基膦苯甲酰)
MDL NumberMFCD01631274
CAS Number169689-05-8
Chemical Name TranslationN,N''-(1S,2S)-1,2-环己烷二基双[2-(二苯基膦基)苯甲酰胺]
PubChem Substance ID329761528
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Trost Ligands
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Trost Ligands

相关文献及参考

  • 1. Trost, B.M. et al. Chem. Rev. 96 , 395, (1996) 摘要
  • 2. Trost, B.M. et al. Chem. Rev. 103 , 2921, (2003) 摘要
  • 3. Trost, B.M. et al. J. Am. Chem. Soc. 124 , 11616, (2004)
  • 4. Aldrichimica Acta 40 , 59, (2007)
  • Trost, B.M. et al. Aldrichimica Acta 40 , 59, (2007)

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Amides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. Trost Ligands - Privileged Ligands and Complexes
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Phosphorus
  1. TROST
  2. Phosphorus
  1. Ligands
  2. Phosphorus

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