Cobalt, [[2,​2'-​[(1R,​2R)​-​1,​2-​cyclohexanediylbis[(​nitrilo-​κN)​methylidyne]​]​bis[4,​6-​bis(1,​1-​dimethylethyl)​phenolato-​κO]​]​(2-​)​]​-​, (SP-​4-​2)​- (R,R)-(-)-N,N'-双(3,5-二叔丁基亚水杨基)-1,2-环己基二胺钴

CAS 176763-62-5 MFCD01631277

化学结构图

176763-62-5
SMILES: CC(C)(C)c1cc2c(c(C(C)(C)C)c1)O[Co]Oc1c(cc(C(C)(C)C)cc1C(C)(C)C)C=N[C@@H]1CCCC[C@H]1N=C2

化学属性

Mol. Formula[[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]Co
Mol. Weight603.74
Melting Point406-412
Appearance red-brown pwdr.
RedoxReduction

别名和识别编码

Chemical NameCobalt, [[2,​2'-​[(1R,​2R)​-​1,​2-​cyclohexanediylbis[(​nitrilo-​κN)​methylidyne]​]​bis[4,​6-​bis(1,​1-​dimethylethyl)​phenolato-​κO]​]​(2-​)​]​-​, (SP-​4-​2)​-
MDL NumberMFCD01631277
PubChem Substance ID24871023
CAS Number176763-62-5
Chemical Name Translation(R,R)-(-)-N,N'-双(3,5-二叔丁基亚水杨基)-1,2-环己基二胺钴
Synonym (R,R)-Jacobsen's catalyst cobalt(II) complex
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Kinetic Resolution, Privileged Ligands and Complexes, SALENs
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Kinetic Resolution, Privileged Ligands and Complexes, SALENs

相关文献及参考

  • 1. Tokunaga, M. et al. Science 277 , 936, (1997) 摘要
  • 2. Jacobsen, E.N. et al. Tetrahedron Lett. 38 , 773, (1997)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Hydrogenation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Kinetic Resolution - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. SALENs - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Others
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes
  5. PyBOX
  1. Jacobsen Ligand
  2. Cobalt
  1. Catalysts
  2. Cobalt

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