1,2-Bis[(2S,5S)-2,5-Diethylphospholano]Benzene(1,5-Cyclooctadiene)Rhodium(I) Tetrafluoroborate 1,2-双[(2S,5S)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I)
CAS 213343-64-7 MFCD01862465
化学结构图
SMILES: [Rh+].CC[C@H]1CC[C@H](CC)P1C1C=CC=CC=1P1[C@H](CC[C@@H]1CC)CC.F[B-](F)(F)F.C1C[CH][CH]CC[CH][CH]1 |^1:32,33,36,37|
化学属性
| Mol. Formula | C30H48BF4P2Rh |
|---|---|
| Mol. Weight | 660.36 |
| Appearance | red-orange xtl. |
| Stability | air sensitive |
别名和识别编码
| Chemical Name | 1,2-Bis[(2S,5S)-2,5-Diethylphospholano]Benzene(1,5-Cyclooctadiene)Rhodium(I) Tetrafluoroborate |
|---|---|
| Synonym | 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {} {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {} {} {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {} {} {} {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {} {} {} {} {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {} {} {} {} {} {} {LY} 1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate {} {} |
| CAS Number | 213343-64-7 |
| Chemical Name Translation | 1,2-双[(2S,5S)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I) |
| PubChem Substance ID | 329761249 |
| MDL Number | MFCD01862465 |
| Canonical SMILES | FB(F)[F-].CC[C@H]1CC[C@H](CC)[P]1(C2=C3C=CC=C2)[Rh+][P]43[C@@H](CC)CC[C@@H]4CC.C5/C=C\CC/C=C\C5.[F-] |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
相关文献及参考
- 1. Sammet, B.; et al., A two step synthesis of a key unit B precursor of cryptophycins by asymmetric hydrogenation Beilstein J. Org. Chem. 7 , 243-245, (2011)
- 2. Chaturvedula, P. V.; et al., Enantioselective synthesis of constrained phenylalanine analogues Tetrahedron Lett. 51 , 5588-5591, (2010)
- 3. Guo, Y.; et al., A General Approach to the Synthesis of β2-Amino Acid Derivatives via Highly Efficient Catalytic Asymmetric Hydrogenation of α-Aminomethylacrylates Adv. Synth. Catal. 352 , 1539-1553, (2010)
- 4. Nair, L. G.; et al., Design and synthesis of novel fluoro amino acids: synthons for potent macrocyclic HCV NS3 protease inhibitors Tetrahedron Lett. 51 , 3057-3061, (2010)
- 5. Terauchi, T.; et al., Stereoselective Synthesis of Triply Isotope-Labeled Ser, Cys, and Ala: Amino Acids for Stereoarray Isotope Labeling Technology Org. Lett. 10 , 2785-2787, (2008)
- 6. Qiu, L.; et al., Enantioselective hydrogenation of α-aminomethylacrylates containing a free N-H group for the synthesis of β-amino acid derivatives Proc. Natl. Acad. Sci. U. S. A. 104 , 16787-16792, (2007)
- 7. Shang, G.; et al., Asymmetric hydrogenation of a-primary and secondary amino ketones: efficient asymmetric syntheses of (-)-arbutamine and (-)-denopamine Chem. Eur. J. 13 , 7780-7784, (2007)
安全信息
GHS Symbol
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