(2R,5R)-(-)-TRANS-2,5-DIMETHYLPYRROLIDINE (2R,5R)-(-)-反-2,5-二甲基吡咯烷

CAS 62617-70-3 MFCD01863020

化学结构图

62617-70-3
SMILES: C[C@@H]1CC[C@@H](C)N1

化学属性

Mol. FormulaC6H13N
Mol. Weight99.17
Refractive indexn20/D 1.431
Density0.852 g/mL at 20 °C(lit.)

别名和识别编码

Chemical Name(2R,5R)-(-)-TRANS-2,5-DIMETHYLPYRROLIDINE
CAS Number62617-70-3
PubChem Substance ID57650066
Beilstein Registry Number4652641
MDL NumberMFCD01863020
Chemical Name Translation(2R,5R)-(-)-反-2,5-二甲基吡咯烷
Synonym (2R,5R)-(-)-反-2,5-二甲基吡咯烷
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Pyrrolidines
  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Pyrrolidines

相关文献及参考

  • 1. R.H. Schlessinger et al. Tetrahedron Lett. 29 , 1489, (1988)
  • 2. R.H. Schlessinger et al. J. Org. Chem. 52 , 708, (1987)
  • 3. N.A. Porter et al. J. Am. Chem. Soc. 111 , 8311, (1989)
  • Beil. 20 ,V,4,146

安全信息

GHS Symbol
WGK Germany3
Hazard Codes F,C
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Risk Statements
  • R11 Highly flammable 非常易燃
  • R22 Harmful if swallowed 吞咽有害
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);

系列性分类


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