2,4,6-Trifluorophenylboronic acid 2,4,6-三氟苯硼酸

CAS 182482-25-3 MFCD01863169

化学结构图

182482-25-3
SMILES: OB(O)C1C(F)=CC(F)=CC=1F

化学属性

Mol. FormulaC6H4BF3O2
Mol. Weight175.90
Melting Pointca 235°
TSCANo

别名和识别编码

Chemical Name2,4,6-Trifluorophenylboronic acid
CAS Number182482-25-3
Alfabeta NameTRIFLUOROPHENYLBORONICACID 246-,,
MDL NumberMFCD01863169
PubChem Substance ID160871045
Synonym 2,4,6-三氟苯硼酸 2,4,6-Trifluorophenylboronic acid
EC Number000-000-0
Beilstein Registry Number8549766
Chemical Name Translation2,4,6-三氟苯硼酸
Reaxys-RN8549766
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分类

  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Trisubstituted Aryl Boronic Acids
  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Trisubstituted Aryl Boronic Acids

相关文献及参考

  • 1. A. Adamczyk-Wozniak, et al., , Quantitative determination of the Lewis acidity of phenylboronic catechol esters - Promising anion receptors for polymer electrolytes Inorg. Chem. Commun. 14 , 1753-1755, (2011)
  • 2. B. M. Crowley, et al., , Expanding the scope of the Cu assisted Suzuki-Miyaura reaction Tetrahedron Lett. 52 , 5055-5059, (2011)
  • 3. T. Kinzel, et al., , A New Palladium Precatalyst Allows for the Fast Suzuki-Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids J. Am. Chem. Soc. 132 , 14073-14075, (2010)
  • 4. T. Korenaga, et al., , Rational electronic tuning of CBS catalyst for highly enantioselective borane reduction of trifluoroacetophenone Chem. Commun. 46 , 8624-8626, (2010)
  • 5. Y. Suzaki and K. Osakada, , Chemical Properties of Mononuclear and Dinuclear Phenylplatinum(II) Hydroxo Complexes with Cod Ligands. Transmetalation of Arylboronic Acids, Coupling of the Phenyl Ligands, and Carbonylation Organometallics 25 , 3251-3258, (2006)
  • 6. K. Osakada, et al., , Diarylpalladium Complexes with a Cis Structure. Formation via Transmetalation of Arylboronic Acids with an Aryliodopalladium Complex and Intramolecular Coupling of the Aryl Ligands, Affording Unsymmetrical Biaryls Organometallics 24 , 190-192, (2005)

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P301+P312
  • P305+P351+P338
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P302+P352

系列性分类


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