Disodium tetracarbonylferrate-dioxane (Collman's Reagent) 四羰基铁酸二钠盐-二噁烷

CAS 59733-73-2 MFCD02091641

化学结构图

59733-73-2
SMILES: [Fe-2].[Fe-2].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[O+]#C[Na].[O+]#C[Na].[O+]#C[Na].[O+]#C[Na].C1COCCO1.C1COCCO1.C1COCCO1

化学属性

Mol. FormulaNa2Fe(CO)4· 1.5C4H8O2
Mol. Weight346.02
TSCANo

别名和识别编码

Chemical NameDisodium tetracarbonylferrate-dioxane (Collman's Reagent)
Synonym Sodium tetracarbonylferrate-dioxane 四羰基铁酸二钠合二噁烷
MDL NumberMFCD02091641
EC Number261-892-7
CAS Number59733-73-2
Chemical Name Translation四羰基铁酸二钠盐-二噁烷
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
Signal word Danger
Hazard statements
  • H351 Suspected of causing cancer 怀疑致癌
  • H331 Toxic if inhaled 吸入中毒
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Packing GroupI
UN Number UN3391
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R23 Toxic by inhalation 吸入有毒
Storage condition Air & Moisture Sensitive
Hazard Codes F,T

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Iron - 铁催化剂

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