Trimethylsilyl 2,2-difluoro-2-(fluorosulfonyl)acetate 三甲基硅烷基 2-(氟磺酰基)二氟乙酸酯

CAS 120801-75-4 MFCD02093343

化学结构图

120801-75-4
SMILES: C[Si](C)(C)OC(=O)C(F)(F)S(=O)(=O)F

化学属性

Mol. FormulaFSO2CF2CO2Si(CH3)3
Mol. Weight250
Boiling Point156
Density1.27
Refractive index1.3660 to 1.3700
Flash Point26°C(lit.)
TSCANo

别名和识别编码

Chemical NameTrimethylsilyl 2,2-difluoro-2-(fluorosulfonyl)acetate
CAS Number120801-75-4
Alfabeta NameTRIMETHYLSILYLFLUOROSULFONYLDIFLUOROACETATE 2()-
MDL NumberMFCD02093343
Synonym 三甲基硅烷基 2-(氟磺酰基)二氟乙酸酯 2,2-Difluoro-2-(fluorosulfonyl)acetic acid trimethylsilyl ester
PubChem Substance ID253660122
Chemical Name Translation三甲基硅烷基 2-(氟磺酰基)二氟乙酸酯
Beilstein Registry Number6400119
LabNetwork Molecule IDLN00119491
Reaxys-RN6400119
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Difluoromethylation, Fluorination Reagents, Others, Synthetic Reagents
  • {SNA} C-C Bond Formation, Chemical Synthesis, Difluoromethylation, Fluorination Reagents, Other Synthetic Reagents for C-C Bond Formation, Synthetic Reagents

安全信息

Warnings FLAMMABLE, CORROSIVE
Packing GroupII
UN Number
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
WGK Germany2
Hazard Codes C
Precautionary statements
  • P303+P361+P353+P310+P363
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P301+P330+P331+P310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P305+P351+P338
  • P405 Store locked up. 上锁保管。
  • P233 Keep container tightly closed. ?保持容器密闭。
Signal word
GHS Symbol
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Hazard Class8/3

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorination Reagents 含氟试剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Others - C-C Bond Formation
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Others - C-C Bond Formation
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Fluorous Chemistry 氟化学

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