Trans-1-Octen-1-Ylboronic Acid 反式-1-辛烯-1-基硼酸

CAS 42599-16-6 MFCD02093734

化学结构图

42599-16-6
SMILES: CCCCCC/C=C/B(O)O

化学属性

Mol. FormulaCH3(CH2)5CH=CHB(OH)2
Mol. Weight156.03
Melting Point100-104 °C(lit.)
TSCANo

别名和识别编码

Chemical NameTrans-1-Octen-1-Ylboronic Acid
CAS Number42599-16-6
Alfabeta NameOCTENYLBORONICACID TRANS-
MDL NumberMFCD02093734
Synonym (E)-1-Octenylboronic acid (2E)-2-Octen-1-ylboronic acid 反式-1-辛烯-1-基硼酸 (E)-1-Octen-1-ylboronic acid (2E)-2-Octen-1-ylboronic acid (E)-1-Octen-1-ylboronic acid (E)-1-Octenylboronic acid trans-1-Octenylboronic acid trans-1-Octenylboronic acid
PubChem Substance ID24874184
Chemical Name Translation反式-1-辛烯-1-基硼酸
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分类

  • {SNA} Alkenyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents
  • Alkenyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents

相关文献及参考

  • 1. Huang, X.-J.; et al., Chiral P-containing palladacycle-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes with alkenyl boronic acids Synlett , 943-946, (2011)
  • 2. Sugiura, M.; et al., Enantioselective conjugate addition of boronic acids to enones catalyzed by O-monoacyltartaric acids Chem. Commun. 46 , 7799-7800, (2010)
  • 3. Chu, L.; Qing, F.-L., Copper-Mediated Oxidative Trifluoromethylation of Boronic Acids Org. Lett. 12 , 5060-5063, (2010)
  • 4. Braun, M.; Richrath, B., Diastereoselective domino Heck-Suzuki reaction: synthesis of substituted methylenetetrahydrofurans Synlett , 968-972, (2009)

安全信息

Warnings IRRITANT
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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