4-Nitrophenylboronic Acid Pinacol Ester 4-硝基苯硼酸频哪醇酯
CAS 171364-83-3 MFCD02179437
化学结构图
SMILES: CC1(C)OB(OC1(C)C)C1C=CC(=CC=1)[N+]([O-])=O
化学属性
| Mol. Formula | C12H16BNO4 |
|---|---|
| Mol. Weight | 249 |
| Melting Point | 112-116 |
别名和识别编码
| Chemical Name | 4-Nitrophenylboronic Acid Pinacol Ester |
|---|---|
| CAS Number | 171364-83-3 |
| Alfabeta Name | NITROPHENYLBORONICACIDPINACOLESTER 4- |
| MDL Number | MFCD02179437 |
| Synonym | 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene 4-(4,4,5,5-四甲基-1,3,2-二氧杂戊硼烷-2-基)硝基苯 |
| PubChem Substance ID | 24883300 |
| Chemical Name Translation | 4-硝基苯硼酸频哪醇酯 |
| Reaxys-RN | 7708816 |
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分类
- Aryl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents
- {SNA} Aryl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents
相关文献及参考
- 1. Y. Li, et al., , Reliable and Diverse Synthesis of Aryl Azides through Copper-Catalyzed Coupling of Boronic Acids or Esters with TMSN3 Chem. Eur. J. 16 , 7969-7972, (2010)
- 2. A. M. Whittaket, et al., , Catalytic SN2'-Selective Substitution of Allylic Chlorides With Arylboronic Esters Org. Lett. 12 , 3216-3218, (2010)
- 3. M. Fukuda, et al., , Syntheses and fluorescence of RNA conjugates having pyrene-modified adenosine and nitrobenzene-modified uridine base pairs Tetrahedron Lett. 51 , 1732-1735, (2010)
- 4. Y. Yamamoto, , The First General and Selective Palladium(II)-Catalyzed Alkoxycarbonylation of Arylboronates: Interplay among Benzoquinone-Ligated Palladium(0) Complex, Organoboron, and Alcohol Solvent Adv. Synth. Catal. 352 , 478-492, (2010)
- 5. J. C. Verheijen, et al., , Discovery of 2-arylthieno[3,2-d]pyrimidines containing 8-oxa-3-azabi-cyclo[3.2.1]octane in the 4-position as potent inhibitors of mTOR with selectivity over PI3K Bioorg. Med. Chem. Lett. 20 , 375-379, (2010)
- 6. K. Mitsudo, et al., , Pd/TEMPO-catalyzed electrooxidative synthesis of biaryls from arylboronic acids or arylboronic esters Tetrahedron 65 , 8384-8388, (2009)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
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