(E)-Prop-1-En-1-Ylboronic Acid 反式-1-丙烯-1-硼酸

CAS 7547-97-9 MFCD02179501

化学结构图

7547-97-9
SMILES: C/C=C/B(O)O

化学属性

Mol. FormulaC3H7BO2
Mol. Weight85.90
Melting Point123-127 °C
Boiling Point175.6±23.0 °C at 760 mmHg

别名和识别编码

Chemical Name(E)-Prop-1-En-1-Ylboronic Acid
Synonym (E)-Prop-1-en-1-ylboronic acid {LY} (E)-Prop-1-en-1-ylboronic acid {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {} {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {} {} {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {} {} {} {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {} {} {} {} {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {} {} {} {} {} {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {} {} {} {} {} {} {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {} {} {} {} {} {} {} {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (E)-Prop-1-en-1-ylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD02179501
PubChem Substance ID6157276
CAS Number7547-97-9
Chemical Name Translation反式-1-丙烯-1-硼酸
LabNetwork Molecule IDLN01368514
InChIInChI=1S/C3H7BO2/c1-2-3-4(5)6/h2-3,5-6H,1H3/b3-2+
Canonical SMILESOB(/C=C/C)O
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分类

  • {SNA} Alkenyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents
  • Alkenyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents

相关文献及参考

  • 1. Yu, D.; et al., Selective palladium-catalyzed C-F activation/carbon-carbon bond formation of polyfluoroaryl oxazolines J. Org. Chem. 77 , 1798-1804, (2012)
  • 2. Fuwa, H.; et al., A new strategy for the synthesis of substituted dihydropyrones and tetrahydropyrones via palladium-catalyzed coupling of thioesters Tetrahedron 67 , 4995-5010, (2011)
  • 3. Jung, J.-W.; et al., Total synthesis of rodgersinol: a survey of the Cu(II)-mediated coupling of ortho-substituted phenols Tetrahedron 66 , 6826-6831, (2010)
  • 4. Crosignani, S.; et al., Discovery of Potent, Selective, and Orally Bioavailable Alkynylphenoxyacetic Acid CRTH2 (DP2) Receptor Antagonists for the Treatment of Allergic Inflammatory Diseases J. Med. Chem. 54 , 7299-7317, (2011)
  • 5. Paz, S.; et al., Tetrahydrobenzothiophene Derivatives: Conformationally Restricted Inhibitors of Type II Dehydroquinase ChemMedChem 6 , 266-272, (2011)
  • 6. Beltran-Rodil, S.; et al., The preparation of substituted pyrazoles from β,β-dibromo-enones by a tandem condensation/Suzuki-Miyaura cross-coupling process Synlett , 602-606, (2010)
  • 7. Zhou, M.-B.; et al., Palladium-catalyzed cross-coupling of electron-poor terminal alkynes with arylboronic acids under ligand-free and aerobic conditions J. Org. Chem. 75 , 5635-5642, (2010)
  • Yu, D.; Shen, Q.; Lu, L., Selective palladium-catalyzed C-F activation/carbon-carbon bond formation of polyfluoroaryl oxazolines J. Org. Chem. 4th ed., 77 , 1798-1804, (2012) 摘要
  • Fuwa, H.; et al., A new strategy for the synthesis of substituted dihydropyrones and tetrahydropyrones via palladium-catalyzed coupling of thioesters Tetrahedron 27-28th ed., 67 , 4995-5010, (2011)
  • Jung, J-W.; et al., Total synthesis of rodgersinol: a survey of the Cu(II)-mediated co

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition -20°C {LY} -20°C 2-8°C {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....

系列性分类


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