4-Chloro-2-methylphenylmagnesium bromide 4-氯-2-甲苯基溴化镁

CAS 480438-47-9 MFCD02260215

化学结构图

480438-47-9
SMILES: CC1C=C(Cl)C=CC=1[Mg]Br

化学属性

Mol. FormulaClC6H3(CH3)MgBr
Mol. Weight229.78
Density0.959 g/mL at 25 °C
Boiling Point65-67 °C
TSCANo

别名和识别编码

Chemical Name4-Chloro-2-methylphenylmagnesium bromide
MDL NumberMFCD02260215
PubChem Substance ID24880022
CAS Number480438-47-9
Synonym 4-氯-2-甲苯基溴化镁 溶液
Chemical Name Translation4-氯-2-甲苯基溴化镁
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分类

  • {SNA} Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

安全信息

WGK Germany3
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P370+P378
  • P403+P235
Signal word Danger
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H351 Suspected of causing cancer 怀疑致癌
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
GHS Symbol
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S8 Keep container dry 保持容器干燥;
Packing GroupII
UN Number UN2924
Risk Statements
  • R11 Highly flammable 非常易燃
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Storage condition Air & Moisture Sensitive
Hazard Codes F,C

系列性分类


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