[1,1′-Bis(Diphenylphosphino)Ferrocene]Tetracarbonylchromium [1,1′-双(二苯基膦)二茂铁]四羰基铬

CAS 67292-31-3 MFCD03427158

化学结构图

67292-31-3
SMILES: [Cr].[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=CC=C1P(C1C=CC=CC=1)[C]1[CH][CH][CH][CH]1.C1=CC=CC=C1P(C1C=CC=CC=1)[C]1[CH][CH][CH][CH]1 |^1:23,24,25,26,27,41,42,43,44,45|

化学属性

Mol. Formula(CO)4Cr(P(C6H5)2C5H4)2Fe
Mol. Weight718.42
Melting Point136-139 °C (dec.)(lit.)
TSCANo

别名和识别编码

Chemical Name[1,1′-Bis(Diphenylphosphino)Ferrocene]Tetracarbonylchromium
MDL NumberMFCD03427158
CAS Number67292-31-3
Synonym [1,1′-双(二苯基膦)二茂铁]四羰基铬(0) Cr(dppf)(CO)4
PubChem Substance ID24879169
Chemical Name Translation[1,1′-双(二苯基膦)二茂铁]四羰基铬
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Chromium

相关文献及参考

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S4 Keep away from living quarters 远离生活区；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Packing GroupIII
UN Number UN3466
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
Storage condition Air Sensitive
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Chromium Catalysis 铬催化剂
  1. Functional Group 官能团索引
  2. phosphine

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