Bis(Pyridine)Iodonium Tetrafluoroborate 双(吡啶)碘鎓四氟硼酸盐
CAS 15656-28-7 MFCD03703393
化学结构图
SMILES: [I+].F[B-](F)(F)F.C1=CC=CC=N1.C1=CC=CC=N1
化学属性
| Mol. Formula | C10H10BF4IN2 |
|---|---|
| Mol. Weight | 371.91 |
| Melting Point | 137-141 °C |
| TSCA | No |
别名和识别编码
| Chemical Name | Bis(Pyridine)Iodonium Tetrafluoroborate |
|---|---|
| CAS Number | 15656-28-7 |
| Alfabeta Name | BISPYRIDINEIODONIUMTETRAFLUOROBORATE () |
| MDL Number | MFCD03703393 |
| Synonym | Bis(pyridine)iodonium tetrafluoroborate {LY} Bis(pyridine)iodonium tetrafluoroborate {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {} |
| Beilstein Registry Number | 4284739 |
| PubChem Substance ID | 125307501 |
| Chemical Name Translation | 双(吡啶)碘鎓四氟硼酸盐 |
| Reaxys-RN | 4284739 |
| Merck Number | 1302 |
| Canonical SMILES | [F-][B+3]([F-])([F-])[F-].[N]1([I+][N]2=CC=CC=C2)=CC=CC=C1 |
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分类
- {SNA} Chemical Synthesis, Hypervalent Iodine, Oxidizing Agents, Synthetic Reagents
相关文献及参考
- Powerful electrophilic iodinating agent; reagent of choice for selective iodinations, under mild conditions, of alkenes: Angew. Chem. Int. Ed., 27, 1715 (1985), acetylenes: J. Org. Chem., 55, 3104 (1990), and aromatic compounds: J. Org. Chem., 58, 2058 (1993); Tetrahedron Lett., 34, 3893 (1993).
- For a brief review on uses of the reagent in synthesis, see: Synlett, 1679 (1999).
- Useful for selective iodination of free phenolic groups in tyrosine residues during solid-phase synthesis: Tetrahedron Lett., 39, 7393 (1998); 40, 7279 (1999). Photolysis of cycloalkanols in the presence of cesium carbonate affords ring-opened ω -iodocarbonyl compounds in good yield: Angew. Chem. Int. Ed., 40, 3389 (2001).
- Photochemical oxidations with the reagent have been reported, e.g. cleavage of 1,2-diols to aldehydes, and oxidation of alcohols to aldehydes or ketones: Chem. Eur. J., 10, 4206 (2004).
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol
- P303+P361+P353+P310+P363
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P405 Store locked up. 上锁保管。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P304+P340+P310
- P305+P351+P338+P310
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H302 Harmful if swallowed 吞食有害
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