Bis(Pyridine)Iodonium Tetrafluoroborate 双(吡啶)碘鎓四氟硼酸盐

CAS 15656-28-7 MFCD03703393

化学结构图

15656-28-7
SMILES: [I+].F[B-](F)(F)F.C1=CC=CC=N1.C1=CC=CC=N1

化学属性

Mol. FormulaC10H10BF4IN2
Mol. Weight371.91
Melting Point137-141 °C
TSCANo

别名和识别编码

Chemical NameBis(Pyridine)Iodonium Tetrafluoroborate
CAS Number15656-28-7
Alfabeta NameBISPYRIDINEIODONIUMTETRAFLUOROBORATE ()
MDL NumberMFCD03703393
Synonym Bis(pyridine)iodonium tetrafluoroborate {LY} Bis(pyridine)iodonium tetrafluoroborate {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(pyridine)iodonium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {}
Beilstein Registry Number4284739
PubChem Substance ID125307501
Chemical Name Translation双(吡啶)碘鎓四氟硼酸盐
Reaxys-RN4284739
Merck Number1302
Canonical SMILES[F-][B+3]([F-])([F-])[F-].[N]1([I+][N]2=CC=CC=C2)=CC=CC=C1
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分类

  • {SNA} Chemical Synthesis, Hypervalent Iodine, Oxidizing Agents, Synthetic Reagents

相关文献及参考

  • Powerful electrophilic iodinating agent; reagent of choice for selective iodinations, under mild conditions, of alkenes: Angew. Chem. Int. Ed., 27, 1715 (1985), acetylenes: J. Org. Chem., 55, 3104 (1990), and aromatic compounds: J. Org. Chem., 58, 2058 (1993); Tetrahedron Lett., 34, 3893 (1993).
  • For a brief review on uses of the reagent in synthesis, see: Synlett, 1679 (1999).
  • Useful for selective iodination of free phenolic groups in tyrosine residues during solid-phase synthesis: Tetrahedron Lett., 39, 7393 (1998); 40, 7279 (1999). Photolysis of cycloalkanols in the presence of cesium carbonate affords ring-opened ω -iodocarbonyl compounds in good yield: Angew. Chem. Int. Ed., 40, 3389 (2001).
  • Photochemical oxidations with the reagent have been reported, e.g. cleavage of 1,2-diols to aldehydes, and oxidation of alcohols to aldehydes or ketones: Chem. Eur. J., 10, 4206 (2004).

安全信息

Warnings MOISTURE SENSITIVE, KEEP COLD
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Moisture & Light Sensitive {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away fr
WGK Germany3
GHS Symbol
Precautionary statements
  • P303+P361+P353+P310+P363
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P405 Store locked up. 上锁保管。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P310
  • P305+P351+P338+P310
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
Signal word
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
UN Number 1759
Packing GroupIII
Hazard Class8

系列性分类


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