Vinylboronic Anhydride Pyridine Complex 乙烯硼酐吡啶络合物

CAS 442850-89-7 MFCD03839940

化学结构图

442850-89-7
SMILES: C=CB1OB(C=C)OB(C=C)O1.c1ccncc1

化学属性

Mol. FormulaC6H9B3O3· C5H5N
Mol. Weight240.67
Melting Point44-52°
TSCANo

别名和识别编码

Chemical NameVinylboronic Anhydride Pyridine Complex
Synonym 2,4,6-三乙烯基环硼氧烷吡啶络合物 Trivinyl-boroxin pyridine complex Trivinylcyclotriboroxane pyridine complex 乙烯硼酐吡啶络合物 O'Shea's reagent
MDL NumberMFCD03839940
PubChem Substance ID2734806
CAS Number442850-89-7
Chemical Name Translation乙烯硼酐吡啶络合物
InChIInChI=1S/C6H9B3O3.C5H5N/c1-4-7-10-8(5-2)12-9(6-3)11-7;1-2-4-6-5-3-1/h4-6H,1-3H2;1-5H
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分类

  • {SNA} Alkenyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents
  • Alkenyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents

相关文献及参考

  • 1. Su, K-J.; et al., Efforts toward Distorted Spiropentanes J. Org. Chem. 21th ed., 75 , 7494-7497, (2010) 摘要
  • 2. Cottineau, B.; Kessler, A.; O'Shea, D. F. , Suzuki-Miyaura cross-coupling: preparation of 2'-vinylacetanilide Org. Synth. 83 , (2006)
  • 3. Ward, A. F.; Wolfe, J. P., Stereoselective Synthesis of Substituted 1,3-Oxazolidines via Pd-Catalyzed Carboamination Reactions of O -Vinyl-1,2-Amino Alcohols Org. Lett. 17th ed., 13 , 4728-4731, (2011) 摘要
  • 4. Taniguchi, Y.; et al., The alkyl-connected 2-amino-6-vinylpurine (AVP) crosslinking agent for improved selectivity to the cytosine base in RNA Bioorg. Med. Chem. 8th ed., 18 , 2894-2901, (2010) 摘要
  • 5. Alacid, E.; Najera, C., Kaiser oxime resin-derived palladacycle: A recoverable polymeric precatalyst in Suzuki-Miyaura reactions in aqueous media J. Organomet. Chem. 11th ed., 694 , 1658-1665, (2009)
  • 6. Milata, V.; Radl, S.; Voltrova, S., Product subclass 3: enol ethers Sci. Synth. 32 , 589-756, (2008)
  • 7. Tsang, D. S.; et al., Stereoselective isomerization of N-allyl aziridines into geometrically stable Z enamines by using rhodium hydride catalysis Chem. Eur. J. 3rd ed., 14 , 886-894, (2008)
  • 8. Aoyama, H.; et al., Kinetic Resolution of Axially Chiral 2,2'-Dihydroxy-1,1'-biaryls by Palladium-Catalyzed Alcoholysis J. Am. Chem. Soc. 30th ed., 127 , 10474-10475, (2005) 摘要
  • 9. Dalili, S.; Yudin, A. K., Transition Metal-Catalyzed Synthesis and Reactivity of N-Alkenyl Aziridines Org. Lett. 6th ed., 7 , 1161-1164, (2005) 摘要
  • 10. Sengupta, S.; et al. , Intramolecular Heck reaction strategy for the synthesis of functionalized tetrahydroanthracenes: a facile formal total synthesis of the linear abietane diterpene, umbrosone Tetrahedron Lett. 9th ed., 46 , 1515-1519, (2005)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Alkenyl Boronic Acids - Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Alkenyl Boronic Acids - Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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