2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl 2-二环己基磷-2′,4′,6′-三异丙基-1,1′-联苯

CAS 564483-18-7 MFCD04117682

化学结构图

564483-18-7
SMILES: CC(C)c1cc(C(C)C)c(-c2ccccc2P(c2ccccc2)c2ccccc2)c(C(C)C)c1

化学属性

Mol. FormulaC33H49P
Mol. Weight476.73
Melting Point186.0 to 190.0 deg-C
TSCANo
Stability对空气敏感
Appearance white pwdr.
Boiling Point569.8°C at 760 mmHg
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical Name2-(Dicyclohexylphosphino)-2,4,6-Triisopropylbiphenyl
CAS Number564483-18-7
Alfabeta NameDICYCLOHEXYLPHOSPHINOTRIPROPYLBIPHENYL I224611()-------,,,''''
MDL NumberMFCD04117682
Synonym XPhos {LY} XPhos {} {LY} XPhos {} {} {LY} XPhos {} {} {} {LY} XPhos {} {} {} {} {LY} XPhos {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} XPhos {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID11155794
Chemical Name Translation2-二环己基磷-2′,4′,6′-三异丙基-1,1′-联苯
LabNetwork Molecule IDLN00155082
Reaxys-RN9448497
InChIInChI=1S/C33H49P/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3
Canonical SMILESCC(C)C1=CC(C(C)C)=CC(C(C)C)=C1C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • {SNA} Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, ChemDose, Chemical Synthesis, Cross-Coupling, Ligands, Specialty Synthesis
  • {SNA} 12 Principles Aligned Products, Buchwald Ligands, Buchwald Ligands and Complexes, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Development Quantities for Research, Greener Alternative Products, Phosphine Compounds
  • {SNA} Buchwald Ligands, Catalysis, Buchwald Ligands, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling,
  • {SNA} Buchwa

安全信息

Warnings IRRITANT, AIR SENSITIVE
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
Signal word Warning
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from lig
Hazard Codes Xn
Restrict -

其他信息

  • Sigma Aldrich:564483-18-7(sigmaaldrich)
  • Alfa Aesar:2-双环己基膦-2',4',6'-三异丙基联苯,98+% 2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 98+%(564483-18-7)
  • 上游原料:乙酸乙酯 --> 甲醇 --> 四氢呋喃 --> 二氯甲烷 --> 溴 --> 四氯化碳 --> 铁粉 --> 镁 --> 氯化亚铜 --> 1,4-苯二酚 --> 1,3,5-三异丙基苯 --> 2-溴氯苯 --> 二环己基氯化膦
  • MOL 文件:564483-18-7.mol
  • 敏感性:Air Sensitive
  • 用途一:偶联反应中，催化体系中配体成份
  • 2-二环己基磷-2,4,6-三异丙基联苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 387140010 2-二环己基磷-2,4,6-三异丙基联苯 2-(Dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl 98+% 1 GR 708元 2010/06/21 387140050 2-二环己基磷-2,4,6-三异丙基联苯 2-(Dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl 98+% 5 GR 2939元 2010/06/21 387140250 2-二环己基磷-2,4,6-三异丙基联苯 2-(Dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl 98+% 25 GR 10871元
  • Acros Organics:2-(二环己基磷)-2',4',6'-三异丙基联苯 2-(Dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl(564483-18-7)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Specialty Synthesis 特殊合成技术
  3. ChemDose™ - Specialty Synthesis
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling - Catalysis and Inorganic Chemistry
  4. Buchwald Ligands and Complexes - Cross-Coupling
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Buchwald Ligands Buchwald 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling 交叉偶联
  4. Basic Phosphine Ligands
  1. Functional Group 官能团索引
  2. phosphine
  1. Buchwald Precatalysts & Ligands
  2. Phosphorus
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Buchwald Precatalysts & Ligands
  2. 96-5500 Buchwald Biaryl Phosphine Ligand Master Kit for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Ligands
  2. 96-5500 Buchwald Biaryl Phosphine Ligand Master Kit for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Phosphine
  2. 96-5500 Buchwald Biaryl Phosphine Ligand Master Kit for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Buchwald Precatalysts & Ligands
  2. 96-5485 Buchwald Biaryl Phosphine Ligand Mini Kit 1 for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Ligands
  2. 96-5485 Buchwald Biaryl Phosphine Ligand Mini Kit 1 for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling
  1. Phosphine
  2. 96-5485 Buchwald Biaryl Phosphine Ligand Mini Kit 1 for Aromatic Carbon-Heteroatom Bond Formation, Suzuki Coupling and Negishi Cross-coupling

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