(S,S,S)-(+)-(3,5-Dioxa-4-Phosphacyclohepta[2,1-a:3,4-a’]Dinaphthalen-4-yl)Bis(1-Phenylethyl)Amine (S,S,S)-(+)-(3,5-二氧杂-4-膦杂环庚烷并[2,1-a:3,4-a’]二萘-4-基)双(1-苯基乙基)胺
CAS 380230-02-4 MFCD04117688
化学结构图
SMILES: CC(c1ccccc1)N(C(C)c1ccccc1)p1oc2ccc3ccccc3c2c2c(ccc3ccccc32)o1
化学属性
| Mol. Formula | C36H30NO2P |
|---|---|
| Mol. Weight | 539.60 |
| Melting Point | 88-89 °C |
| Appearance | off-white pwdr. |
| Stability | moisture sensitive |
别名和识别编码
| Chemical Name | (S,S,S)-(+)-(3,5-Dioxa-4-Phosphacyclohepta[2,1-a:3,4-a’]Dinaphthalen-4-yl)Bis(1-Phenylethyl)Amine |
|---|---|
| Synonym | (S,S,S)-(+)-(3,5-二氧杂-4-磷杂环庚二烯并[2,1-a:3,4-a']二萘-4-基)二(1-苯基乙基)胺 (+)-N,N-Bis[(1S)-1-phenylethyl]- dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin- 4-amine, (11bR) |
| MDL Number | MFCD04117688 |
| PubChem Substance ID | 11731247 |
| CAS Number | 380230-02-4 |
| Chemical Name Translation | (S,S,S)-(+)-(3,5-二氧杂-4-膦杂环庚烷并[2,1-a:3,4-a’]二萘-4-基)双(1-苯基乙基)胺 |
| InChI | InChI=1S/C36H30NO2P/c1-25(27-13-5-3-6-14-27)37(26(2)28-15-7-4-8-16-28)40-38-33-23-21-29-17-9-11-19-31(29)35(33)36-32-20-12-10-18-30(32)22-24-34(36)39-40/h3-26H,1-2H3/t25-,26-/m0/s1 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DSM MonoPhos Phosphoramidites, Privileged Ligands and Complexes
相关文献及参考
- 1. Synlett , 1375, (2001)
- 2. Org. Lett. 4 , 3835, (2002) 摘要
- 3. J. Org. Chem. 70 , 7451, (2005) 摘要
- 4. Org. Biomolecular Chem. 4 , 1278, (2006)
- Marcovic´, D.; Hartwig, J. F. J. Am. Chem. Soc. 129 , (2007)
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